“…[1] In addition, bulk α-Ag 2 S shows good photoelectric and thermoelectric properties, which allow to use this material in diverse optical and electronic devices, such as IR detectors, photoconductors, [2] photosensitive materials for recording media, [3] solar-selective coatings, [4] ion-selective electrode membranes, [5] gas sensors, [6] and solid state memory devices. [7,8] For the preparation of silver sulfide thin films, several synthetic methodologies including chemical bath deposition, [9] spray pyrolysis, [1,10] thermal evaporation, [3,11,12] molecular beam epitaxy, [13] sol-gel processes, [14] sulfurization, [15] successive ionic-layer adsorption and reaction, [16] electrodeposition, [17] electroless deposition, [18] electrochemical ion-exchange processes, [19] direct conversion, dip-coat-1 GC-MS, and NMR experiments. Because of the better solubility of 3b, this complex was tested for Ag 2 S spin-coating deposition studies on different substrates (SiO 2 /Si, TiN/SiO 2 / Si, glass) with subsequent annealing at 450°C under a N 2 atmosphere.…”