The cavitation effect, as a kind
of geochemical phenomenon,
widely
exists under intense hydrodynamic circumstances, turbulent streams,
earthquakes, or waterfalls and anywhere else where a shear force abruptly
breaks the continuity of liquid surfaces. The development of an efficient
and cheap sonocatalyst is hence one of the effective ways to utilize
the cavitation effect to harness energy. In this study, we use a flower-like
cobalt nitride nanowires catalyst with rich nitrogen-vacancy nanostructures
to achieve efficient sonocatalytic hydrogen production in various
water resources. In pure water, an exceptional sonocatalytic hydrogen
generation rate of 28.5 μmol g–1 h–1 is delivered by the flower-like cobalt nitride nanowires. More interestingly,
hydrogen peroxide, a high-value oxidation product, is also detected
in the liquid phase after ultrasonic wave vibrations. Due to the acid/alkali
resistance and corrosion resistance of the transition metal nitrides
(TMNs), cobalt nitride nanowires can also produce hydrogen in acidic
water, alkaline water, seawater, and wastewater. Enriched active sites
in cobalt nitride nanowires greatly promote the recombination of radicals
generated by the implosion of cavitation bubbles, which promotes sonochemical
reaction efficiency. In addition, the cobalt nitride nanowire catalyst
displays excellent stability and reusability during the sonochemical
catalytic reaction. The findings are anticipated to be useful for
further research on transition metal nitride materials as prospective
sonocatalysts for energy conversion and environmental remediation.