Sonochemical synthesis and characterization of a novel hetro-binuclear metal organic nano polymer based on picolinic acid ligand

Hayati, Payam; Souri, Bagher; Rezvani, Ali Reza; Morsali, Ali; Gutierrez, Angel

doi:10.1016/j.molstruc.2017.09.006

Cited by 18 publications

(4 citation statements)

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“…The Scherrer formula was used for estimating the particle average size, which was obtained as 65 nm. ].½H2O}n (pyc: 2-picolinate, C6H4NO2 − ) using the sonochemical method [92]. The polymer's crystal structure consisted of a 1D CP complex, in which the lead ion had a coordination number of seven (Figure 13).…”

Section: Synthesis Of Lead Azide Coordination Polymersmentioning

confidence: 99%

“…The bond distances between 2.41 and 2.78 Å were in the range typical for Pb-O and Pb-N bonds and the angles between Pb-O-Pb and Pb-N-Pb were 145.88° and 109.94°, respectively. ) using the sonochemical method [92]. The polymer's crystal structure consisted of a 1D CP complex, in which the lead ion had a coordination number of seven (Figure 13).…”

Section: Synthesis Of Lead Azide Coordination Polymersmentioning

confidence: 99%

“…Copyright 2011, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Gutierrez et al (2017) developed a facile procedure for the preparation of NPs of one novel Pb and K coordination compound {[Pb6(pyc)6(N3)7K].½H2O}n (pyc: 2-picolinate, C6H4NO2 − ) using the sonochemical method[92]. The polymer's crystal structure consisted of a 1D CP complex, in which the lead ion had a coordination number of seven (Figure13).…”

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Lead(II)-Azido Metal–Organic Coordination Polymers: Synthesis, Structure and Application in PbO Nanomaterials Preparation

Dadashi

Khaleghian

Hanifehpour³

et al. 2022

Nanomaterials

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The current study aims to explain recent developments in the synthesis of Pb(II)-azido metal-organic coordination polymers. Coordination polymers are defined as hybrid materials encompassing metal-ion-based, organic linkers, vertices, and ligands, serving to link the vertices to 1D, 2D, or 3D periodic configurations. The coordination polymers have many applications and potential properties in many research fields, primarily dependent on particular host–guest interactions. Metal coordination polymers (CPs) and complexes have fascinating structural topologies. Therefore, they have found numerous applications in different areas over the past two decades. Azido-bridged complexes are inorganic coordination ligands with higher fascination that have been the subject of intense research because of their coordination adaptability and magnetic diversity. Several sonochemical methods have been developed to synthesize nanostructures. Researchers have recently been interested in using ultrasound in organic chemistry synthetics, since ultrasonic waves in liquids accelerate chemical reactions in heterogeneous and homogeneous systems. The sonochemical synthesis of lead–azide coordination compounds resulted from very fantastic morphologies, and some of these compounds are used as precursors for preparing nano lead oxide. The ultrasonic sonochemistry approach has been extensively applied in different research fields, such as medical imaging, biological cell disruption, thermoplastic welding, food processing, and waste treatment. CPs serve as appropriate precursors for preparing favorable materials at the nanoscale. Using these polymers as precursors is beneficial for preparing inorganic nanomaterials such as metal oxides.

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Section: Synthesis Of Lead Azide Coordination Polymersmentioning

confidence: 99%

Section: Synthesis Of Lead Azide Coordination Polymersmentioning

confidence: 99%

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confidence: 99%

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Lead(II)-Azido Metal–Organic Coordination Polymers: Synthesis, Structure and Application in PbO Nanomaterials Preparation

Dadashi

Khaleghian

Hanifehpour³

et al. 2022

Nanomaterials

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“…Since the surface‐to‐volume ratio is high in these compounds, they have a lot more activities than their bulk . Therefore, a lot of studies have been carried out to synthesize these NCPs …”

Section: Introductionmentioning

confidence: 99%

Achieving Different Morphologies for a Zinc(II) Coordination Polymer by Green Sonochemical Synthesis and New Precursors for the Preparation of Zinc(II)oxide

et al. 2019

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A new 2D zinc(II) coordination polymer(CP) 1, [Zn(N 3 )(L)] n (1), [L = 2-picolinate] has been synthesized using branch tube approach. Nano and micro structures of CP 1 were synthesized using sonochemical technique in diverse conditions (different times and solvents) and they were identified by elemental analysis, FT-IR spectra, scanning electron microscopy (SEM) and powder X-ray diffraction (PXRD). Single-crystal X-ray studies show that CP1 contains Zn(II) atoms with different coordination geometries (tetrahedral and octahedral). The effects of solvents and reaction time on the morphology and size of the nano and microstructure of CP 1 were also evaluated. The results showed that change in reaction time has almost no effect on the size of particles, but change in solvent leads to changes in the morphology of particles.

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Metal–organic framework

Karimi

Mehrabadi

Farsadrooh

et al. 2021

Interface Science and Technology

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Sonochemical synthesis and characterization of a novel hetro-binuclear metal organic nano polymer based on picolinic acid ligand

Cited by 18 publications

References 50 publications

Lead(II)-Azido Metal–Organic Coordination Polymers: Synthesis, Structure and Application in PbO Nanomaterials Preparation

Lead(II)-Azido Metal–Organic Coordination Polymers: Synthesis, Structure and Application in PbO Nanomaterials Preparation

Achieving Different Morphologies for a Zinc(II) Coordination Polymer by Green Sonochemical Synthesis and New Precursors for the Preparation of Zinc(II)oxide

Metal–organic framework

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