Sonochemistry and sonocatalysis of iron carbonyls

Suslick, Kenneth S.; Schubert, Paul F.; Goodale, J. W.

doi:10.1021/ja00414a054

Cited by 80 publications

(26 citation statements)

References 3 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…A radical reaction product has never been produced with mechanical stirring, whereas other radical reaction products have been obtained under ultrasonic irradiation. (7.11) The sonochemical reaction of a metal carbonyl in a hydrocarbon solvent is one of only a few examples where the detailed reaction mechanism has been studied [14]. The sonolysis of the solvent acetic acid may also be involved [13].…”

Section: Sonochemistry In Homogeneous Systemsmentioning

confidence: 99%

“…As described in the section on homogeneous sonochemistry, sonochemistry and photochemistry usually give different results [14,15]. Usually, light produces excited species in a homogeneously dispersed state, whereas ultrasound produces them in a heterogeneously and more localized dispersed state originating in a cavitation bubble.…”

Section: Photochemistry Under Ultrasonic Irradiationmentioning

confidence: 99%

See 1 more Smart Citation

Application of Ultrasound to Organic Synthesis

Kimura

2015

Sonochemistry and the Acoustic Bubble

View full text Add to dashboard Cite

Section: Sonochemistry In Homogeneous Systemsmentioning

confidence: 99%

Section: Photochemistry Under Ultrasonic Irradiationmentioning

confidence: 99%

Application of Ultrasound to Organic Synthesis

Kimura

2015

Sonochemistry and the Acoustic Bubble

View full text Add to dashboard Cite

“…The use and study of ultrasound for material processing is a very matured and popular concept. Sonochemistry arose into prominence during the early 80's, when Suslick started wreaking havoc inside solutions with his ultrasonic machine gun [35] [36][37] [38]. Nanostructures with unique physical and chemical property have evolved to lend new and improved applications across multiple fields [39] [40][41] [42] [43][44] [45].…”

Section: Introductionmentioning

confidence: 99%

Sonochemistry: Science and Engineering

Pokhrel

Vabbina

Pala

2016

Ultrasonics Sonochemistry

314

127

View full text Add to dashboard Cite

Sonochemistry offers a simple route to nanomaterial synthesis with the application of ultrasound. The tiny acoustic bubbles, produced by the propagating sound wave, enclose an incredible facility where matter interact among at energy as high as 13 eV to spark extraordinary chemical reactions. Within each period - formation, growth and collapse of bubbles, lies a coherent phase of material formation. This effective yet highly localized method has facilitated synthesis of various chemical and biological compounds featuring unique morphology and intrinsic property. The benign processing lends to synthesis without any discrimination towards a certain group of material, or the substrates where they are grown. As a result, new and improved applications have evolved to reach out various field of science and technology and helped engineer new and better devices. Along with the facile processing and notes on the essence of sonochemistry, in this comprehensive review, we discuss the individual and mutual effect of important input parameters on the nanomaterial synthesis process as a start to help understand the underlying mechanism. Secondly, an objective discussion of the diversely synthesized nanomaterial follows to divulge the easiness imparted by sonochemistry, which finally blends into the discussion of their applications and outreach.

show abstract

“…Indeed, it is known to enhance some processes through a physical phenomenon called cavitation, which is the formation, growth and collapse of bubbles in an elastic liquid. 9 By imploding, these bubbles create local high pressure (up to 1000 bar) and high temperature (up to 5000 K) that lead to high-energy radical mechanisms 10 and also create some interesting physical effects such as micromixing, mass transport or reduction of particle size. 11 As the metathesis using ammonium salt is a heterogeneous process, the ultrasound methods could be of great benefit since they are able to reduce ammonium salt particles and, thus, increase their reactivity.…”

mentioning

confidence: 99%