“…Optical field enhances free electron temperature, Te, to the order of 10 4 -10 5 K, while the temperature of neighboring molecules or ions, Tm, is much lower [18]. Within the following 10 −9 -10 −8 s, Tm rapidly ascents through energy transfer due to elastic and inelastic collision between hot electrons and the surrounding air molecules (nitrogen and oxygen), until thermal equilibrium appears [19,20]. This sudden increase of localized gas temperature gives rise to a shock wave that persists for a short distance, then relaxing into acoustic wave [21,22].…”