2016
DOI: 10.1007/s10661-016-5313-4
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Sorption, desorption, and speciation of Cd, Ni, and Fe by four calcareous soils as affected by pH

Abstract: The sorption, desorption, and speciation of cadmium (Cd), nickel (Ni), and iron (Fe) in four calcareous soils were investigated at the pH range of 2-9. The results indicated that sorption of Fe by four soils was higher than 80 % at pH 2, while in the case of Cd and Ni was less than 30 %. The most common sequence of metal sorption at pH 2-9 for four soils was in the order of Fe ≫ Ni > Cd. Cadmium and Ni sorption as a function of pH showed the predictable trend of increasing metal sorption with increase in equil… Show more

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Cited by 49 publications
(19 citation statements)
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“…Page et al ( 2014 ) claim that soil reaction cannot be treated as a sole indicator of the mobility of heavy metals and their availability to plants, or the risk of their migration to the water environment. Tahervand and Jalali ( 2016 ) demonstrated that sorption and desorption of heavy metals in soil depended not only on the soil’s pH but also on its content of organic matter and calcium carbonate and on the chemical properties of a given metal. Cd and Ni are most strongly adsorbed in soil with a high content of organic matter, while Fe in soil rich in CaCO 3 .…”
Section: Resultsmentioning
confidence: 99%
“…Page et al ( 2014 ) claim that soil reaction cannot be treated as a sole indicator of the mobility of heavy metals and their availability to plants, or the risk of their migration to the water environment. Tahervand and Jalali ( 2016 ) demonstrated that sorption and desorption of heavy metals in soil depended not only on the soil’s pH but also on its content of organic matter and calcium carbonate and on the chemical properties of a given metal. Cd and Ni are most strongly adsorbed in soil with a high content of organic matter, while Fe in soil rich in CaCO 3 .…”
Section: Resultsmentioning
confidence: 99%
“…Similarly, Cr levels were below the limits reported by Oliveira [33], who observed concentrations between 5 and 100 mg g −1 to be toxic for ryegrass. In turn, Cd contents were below the quantifiable limits of the methodology, a result that could be due to the low solubility of this metal at neutral and basic pH [34].…”
Section: Resultsmentioning
confidence: 99%
“…The desorption amount was often used as an index to indicate the adsorption strength, and can generally be used to illustrate the bonding degree of the colloidal surface active adsorption position with heavy metal ions (Tahervand et al, 2016(Tahervand et al, , 2017. The desorption isotherm and desorption rate of Ni on bottom sediment and soil are shown in Figure 3.…”
Section: The Desorption Of Ni In Sediment and Black Soilmentioning
confidence: 99%