Sorption of organic compounds from aqueous solutions by glycidyl methacrylate-styrene-ethylene dimethacrylate terpolymers

Podlesnyuk, V. V.; Hradil, J.; Marutovskii, R. M.; Клименко, Н. А.; Fridman, L. E.

doi:10.1016/s1381-5148(97)00065-5

Cited by 17 publications

(9 citation statements)

References 13 publications

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“…The poly(GMA‐ co ‐EGDMA) copolymer is frequently used as a starting material for various kinds of functionalization due to the presence of the reactive epoxy groups and macroporous structure . Particle size distribution and pore size distribution obtained from the porosity measurements of the poly(GMA‐ co ‐EGDMA) copolymer and Ag/G‐NH 2 composites presented in Fig.…”

Section: Resultsmentioning

confidence: 99%

“…Crosslinked macroporous poly(glycidyl methacrylate‐co‐ethylene glycol dimethacrylate) (poly(GMA‐ co ‐EGDMA)) resins, due to the possibility to control their properties (size, porosity, etc.) and due to the presence of reactive epoxy group, have found a variety of applications, such as sorbents and column packaging in different types of chromatograph , enzyme supports , in biotechnological and biomedical applications , for heavy and precious metal sorption , and the sorption of organic compounds . On the other hand, relatively little published data concerning composites based on poly(GMA‐ co ‐EGDMA) copolymer and noble metal particles can be found in the literature .…”

Section: Introductionmentioning

confidence: 99%

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Synthesis, characterization, and antimicrobial activity of silver nanoparticles on poly(GMA‐co‐EGDMA) polymer support

et al. 2015

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Poly(glycidyl methacrylate‐co‐ethylene glycol dimethacrylate) (poly(GMA‐co‐EGDMA) macroporous copolymer decorated with silver nanoparticles was prepared by a modification of poly(GMA‐co‐EGDMA) in the reaction with arginine, and consequent reduction of silver ions with amino groups. The mercury intrusion porosimetry, transmission electron microscopy, X‐ray diffraction, UV–vis reflection spectroscopy, and inductively coupled plasma atomic emission measurements were used to characterize obtained composite. The coordination of silver nanoparticles to the poly(GMA‐co‐EGDMA) copolymer was studied using infrared spectroscopy. Time dependence and concentration dependence of the antimicrobial efficiency of composite were tested against Gram‐negative bacteria Escherichia coli, Gram‐positive bacteria Staphylococcus aureus, and fungus Candida albicans. The composite ensured maximum reduction of both bacteria, while the fungi reduction reached satisfactory 96.8%. Preliminary antimicrobial efficiency measurements using laboratory flow setup indicated potential applicability of composite for wastewater treatment. POLYM. COMPOS., 38:1206–1214, 2017. © 2015 Society of Plastics Engineers

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Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Synthesis, characterization, and antimicrobial activity of silver nanoparticles on poly(GMA‐co‐EGDMA) polymer support

et al. 2015

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“…[18][19][20] Activated carbons as adsorbents for the removal of phenolic compounds are the most widely used method for water treatment. Macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)s have been used for the removal of organic pollutants, [28][29][30] due to their chemical resistance, regenerability and reuse in adsorption processes. 5 Other adsorbents used for the removal of phenols from wastewaters are: zeolites, 2 bentonites, 3,22 organo-modified bentonites, 23 synthetic resins, 24 and different polymeric materials.…”

Section: Introductionmentioning

confidence: 99%

Sorption of different phenol derivatives on functionalized macroporous nanocomposite of poly (glycidyl methacrylate-co-ethylene glycol dimethacrylate) and acid modified bentonite

Marinović¹,

Milutinovic-Nikolic²,

Nastasović

et al. 2014

JSCS

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Macroporous nanocomposite of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) and acid modified bentonite was prepared by radical suspension copolymerization. Nanocomposite was functionalized with diethylenetriamine (DETA), by ring-opening reaction of the pendant epoxy groups. Functionalization was performed in order to enable phenol derivatives sorption. This new, not sufficiently investigated material, with developed porous structure was denoted CP-S A -DETA. In this study, the influence of temperature on 4-nitrophenol (4NP) sorption on CP-S A -DETA was investigated. The chemisorption was estimated as dominant process since activation energy of sorption of 4NP of 54.8 kJ mol -1 was obtained. After determining the optimal sorption conditions for 4NP, the sorption of 2-nitrophenol (2NP) and 2-chloro-4-nitrophenol (2Cl4NP) on CP-S A -DETA was investigated with respect to pH, initial concentration and contact time. The 2NP sorption was seldom tested, while according to our knowledge, the 2Cl4NP sorption was not investigated. The isotherm data were best fitted with Langmuir model, while the sorption dynamics obeyed the pseudo-second-order kinetic model for all derivatives.

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“…The porous structure of these copolymers can be controlled by adjusting the reaction mixture composition. [22][23][24][25] These copolymers were proven to be very useful as sorbents and column packings in different types of chromatography, 26,27 as enzyme supports, 28 in biotechnological and biomedical applications, 29 for heavy and precious metal sorption, 30-32 the sorption of organic compounds, 33,34 etc. However, there is a lack of literature data on the textile dyes sorption by copolymers based on GMA.…”

Section: Introductionmentioning

confidence: 99%

Sorption of textile dye from aqueous solution by macroporous amino‐functionalized copolymer

Sandić

Nastasović

Jović-Jovičić

et al. 2011

J of Applied Polymer Sci

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Macroporous poly(glycidyl methacrylate-coethylene glycol dimethacrylate) (PGME) was synthesized by suspension copolymerization and functionalized with diethylene triamine (PGME-deta). The effect of pH, contact time, and sorbent mass on sorption efficiency of initial and functionalized copolymer sample for removal of Acid Orange 10 dye from aqueous solutions was studied. No dye was sorbed by nonfunctionalized copolymer, indicating that sorption of Acid Orange 10 by PGME-deta is specific, through amino groups. The isotherm data are best fitted by Langmuir model, indicating homogeneous distribution of active sites in PGME-deta as well as monolayer sorp-tion. Sorption kinetics study showed that the sorption of Acid Orange 10 by PGME-deta obeys the pseudo-secondorder kinetic model. It was shown that PGME-deta selectively sorbs Acid Orange 10 from binary solution with Bezaktiv Rot reactive dye. The comparison of sorption characteristics of PGME-deta with activated carbon showed that this functionalized copolymer might be used as an alternative sorbent for textile dyes.

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Sorption of organic compounds from aqueous solutions by glycidyl methacrylate-styrene-ethylene dimethacrylate terpolymers

Cited by 17 publications

References 13 publications

Synthesis, characterization, and antimicrobial activity of silver nanoparticles on poly(GMA‐co‐EGDMA) polymer support

Synthesis, characterization, and antimicrobial activity of silver nanoparticles on poly(GMA‐co‐EGDMA) polymer support

Sorption of different phenol derivatives on functionalized macroporous nanocomposite of poly (glycidyl methacrylate-co-ethylene glycol dimethacrylate) and acid modified bentonite

Sorption of textile dye from aqueous solution by macroporous amino‐functionalized copolymer

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