Sorption thermosiphon apparatus (STA): A novel and accurate system for gas mixtures sorption measurements

Rezende, Carolina Guedes Fioravante; Amaral, Rafael Aislan; Habert, Alberto Cláudio; Borges, Cristiano Piacsek

doi:10.1016/j.polymertesting.2020.106382

Cited by 1 publication

(1 citation statement)

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“…The sorption measurement apparatus is used in many fields related to geological [6][7][8][9], chemical [10][11][12][13], biological [14,15], environmental [16,17] sciences as well as many others. From the point of view of methods of measuring the sorption process, there are many techniques, including breakthrough, volumetric, gravimetric, desorption, and many special ones [18].…”

Section: Introductionmentioning

confidence: 99%

The high-pressure sorptomat – a novel apparatus for volumetric sorption studies under isobaric high gas pressure conditions

Kudasik,

Anioł,

Skoczylas

2022

Metrology and Measurement Systems

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As part of the work the high-pressure sorptomat -a novel apparatus for sorption tests under conditions of high gas pressure was developed. The sorption measurement is carried out using the volumetric method, and the precise gas flow pressure regulator is used in the device to ensure isobaric conditions and regulate the sorption pressure in the range of 0-10 MPa. The uniqueness and high precision of sorption measurements with the constructed apparatus are ensured by the parallel use of many pressure sensors with a wide measurement range as well as high precision of measurement -due to the use of precise pressure sensors. The obtained results showed, i.a. that the time of reaching the isobaric conditions of the measurement is about 6-7 seconds and it is so short that it can be considered a quasi-step initiation of sorption processes. Moreover, the results of the measurement pressure stabilization tests, during the CO 2 sorption test on activated carbon, have shown that the built-in pressure regulator works correctly and ensures isobaric sorption measurement conditions with the precision of pressure stabilization of ±1% of the measurement pressure. The maximum range of sorption measurement using the high-pressure sorptomat is 0-86 400 cm 3 /g, and the maximum measurement uncertainty is ±2% of the measured value. The activated carbon sample used for the tests was characterized by a high sorption capacity, reaching 104.4 cm 3 /g at a CO 2 pressure of 1.0 MPa.

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