This research addresses the problem of globally stabilizing a distinct category of fractional-order power systems (F-OP) by employing an observer-based methodology. To address the inherent nonlinearity in these systems, we leverage a Takagi–Sugeno (TS) fuzzy model. The practical stability of the proposed system is systematically established through the application of a sum-of-squares (SOS) approach. To demonstrate the robustness and effectiveness of our approach, we conduct simulations of the power system using SOSTOOLS v3.00. Our study contributes to advancing the understanding of F-OP and provides a practical framework for their global stabilization.