It has been speculated that the composition of the exosphere is related to the composition of Mercury's crustal materials. If this relationship is true, then inferences regarding the bulk chemistry of the planet might be made from a thorough exospheric study. The most vexing of all unsolved problems is the uncertainty in the source of each component. Historically, it has been believed that H and He come primarily from the solar wind (Goldstein, B.E., et al. in J. Geophys. Res. 86:5485-5499, 1981), Na and K come from volatilized materials partitioned between Mercury's crust and meteoritic impactors (Hunten, D.M., et al. in Mercury, pp. 562-612, 1988; Morgan, T.H., et al. in Icarus 74:156-170, 1988; Killen, R.M., et al. in Icarus 171:1-19, 2004b). The processes that eject atoms and molecules into the exosphere of Mercury are generally considered to be thermal vaporization, photon-stimulated desorption (PSD), impact vaporization, and ion sputtering. Each of these processes has its own temporal and spatial dependence. The exosphere is strongly influenced by Mercury's highly elliptical orbit and rapid orbital speed. As a consequence the surface undergoes large R. Killen ( )