Abstract. Lucknow is the capital of India's largest state, Uttar Pradesh, one of South
Asia's most polluted urban cities. Tropospheric photochemistry relies on
non-methane volatile organic compounds (NMVOCs), which are ozone and
secondary organic aerosol precursors. Using the proton-transfer reaction
time-of-flight mass spectrometer (PTR-ToF-MS) at an urban background site in Lucknow, the chemical characterisation of NMVOCs was performed in real time from December 2020 to May 2021. About ∼ 173 NMVOCs from m/z 31.018 to
197.216 were measured during the study period, including aromatics,
non-aromatics, oxygenates, and nitrogen-containing compounds. The campaign
daily mean concentrations of the NMVOCs were 125.5 ± 37.5 ppbv. The
NMVOC daily average concentrations were about ∼ 30 % higher during the winter months (December–February) than in summer (March–May). The oxygenated volatile organic compounds and aromatics were the dominant VOC
families, accounting for ∼ 57 %–80 % of the total NMVOC concentrations. Acetaldehyde, acetone, and acetic acid were the major NMVOC
species, 5–15 times higher than the other species. An advanced multi-linear engine (ME-2) model was used to perform the NMVOC source apportionment using positive matrix factorisation (PMF). It resolves the five main sources
contributing to these organic compounds in the atmosphere. They include
traffic (23.5 %), two solid fuel combustion factors, SFC 1 (28.1 %) and SFC 2 (13.2 %), secondary volatile organic compounds (SVOCs) (18.6 %), and
volatile chemical products (VCPs) (16.6 %). Aged and fresh emissions from
solid fuel combustion (SFCs 1 and 2) were the dominant contributors to the total NMVOCs, and compounds related to these factors had a high secondary organic aerosol (SOA) formation potential. Interestingly, the traffic factor was the second-highest contributor to the total NMVOCs, and compounds related to this factor had a high ozone formation potential. Significant differences in the composition of the two solid fuel combustions indicate the influence of local
emissions and transport of regional pollution to the city. The high
temperature during summer leads to more volatilisation of oxygenated VOCs,
related to the VCP factor. The study is the first attempt to highlight the sources of NMVOCs and their contribution to secondary pollutant (SOA and
O3) formation in the city of Lucknow during winter and summer. The insights from the study would help various stakeholders to manage primary and secondary pollutants within the city.