This paper reports on space charge evolution in crosslinked polyethylene (XLPE) planar samples approximately 1.20 mm thick subjected to electric stress level of 30 kV dc /mm at four temperatures 25, 50, 70 and 90 o C for 24 h. Space charge profiles in both asreceived and degassed samples were measured using the laser induced pressure pulse (LIPP) technique. The dc threshold stresses at which space charge initiates are greatly affected by testing temperatures. The results suggest that testing temperature has numerous effects on space charge dynamics such as enhancement of ionic dissociation of polar crosslinked by-products, charge injection, charge mobility and electrical conductivity. Space charge distributions of very different nature were seen at lower temperatures when comparing the results of as-received samples with degassed samples. However at higher temperature, the space charge distribution took the same form, although of lower concentration in degassed samples. Space charge distributions are dominated by positive charge when tested at high temperatures regardless of sample treatment and positive charge propagation enhances as testing temperature increases. This can be a major cause of concern as positive charge propagation has been reported to be related to insulation breakdown.