Space‐Confined Growth of Ultrathin P‐Type GeTe Nanosheets for Broadband Photodetectors

Abstract

As p‐type phase‐change degenerate semiconductors, crystalline and amorphous germanium telluride (GeTe) exhibit metallic and semiconducting properties, respectively. However, the massive structural defects and strong interface scattering in amorphous GeTe films significantly reduce their performance. In this work, two‐dimensional (2D) p‐type GeTe nanosheets are synthesized via a specially designed space‐confined chemical vapor deposition (CVD) method, with the thickness of the GeTe nanosheets reduced to 1.9 nm. The space‐confined CVD method improves the crystallinity of ultrathin GeTe by lowering the partial pressure of the reactant gas, resulting in GeTe nanosheets with excellent p‐type semiconductor properties, such as a satisfactory on/off ratio of 105. Temperature‐dependent electrical measurements demonstrate that variable‐range hopping and optical‐phonon‐assisted hopping mechanisms dominate transport behavior at low and high temperatures, respectively. GeTe devices exhibit significantly high responsivity (6589 and 2.2 A W−1 at 633 and 980 nm, respectively) and detectivity (1.67 × 1011 and 1.3 × 108 Jones at 633 and 980 nm, respectively), making them feasible for broadband photodetectors in the visible to near‐infrared range. Furthermore, the fabricated GeTe/WS2 diode exhibits a rectification ratio of 103 at zero gate voltage. These satisfactory p‐type semiconductor properties demonstrate that ultrathin GeTe exhibits enormous potential for applications in optoelectronic interconnection circuits.

Controlled Synthesis of Ultrathin Cu2Te Nanosheets for High-Performance Photodetectors

“…The ultrathin Cu 2 Te nanosheets were synthesized on a SiO 2 /Si substrate through a modified spatially confined CVD method using copper iodide (CuI) powders and tellurium (Te) powders as the precursors shown in Figure a. A smaller, one-end-closed inner quartz tube is placed in a larger tube furnace to form a specially designed CVD system with the purpose of reducing the reactants’ concentration and nucleation density, thus inhibiting the thermodynamic process and promoting epitaxial growth. − More details of sample synthesis are described in the Methods section. Figure b displays the top- and side-view structures of the layered Cu 2 Te.…”