Volatile
organic compounds (VOCs) affect oxidant loadings and secondary
organic aerosol formation in the lower atmosphere. The marine environment
is thought to be an important global source of biogenic VOCs (BVOCs).
Despite that, there is relatively limited knowledge on coastal upwelling
BVOCs. This paper presents sea-to-air fluxes and spatial and temporal
distributions of the BVOCs, isoprene and monoterpenes, in the coastal
upwelling region off the east coast of Peninsular Malaysia (ECPM).
The overall fluxes ranged between 107 and 108 molecules/cm2/s, which is comparable with open ocean
values. Isoprene dominated the overall fluxes with an average percentage
of 65% compared to monoterpenes (total) (35%). Among the monoterpene
compounds, β-pinene showed the highest average flux, followed
by α-pinene and limonene. The spatial distribution suggests
that isoprene fluxes potentially correspond to the sea surface water
nutrients compared to monoterpenes. A significant relationship between
isoprene and monoterpene (total) fluxes was observed (R = 0.73, P < 0.01), which may indicate that both
isoprene and monoterpenes are controlled by an identical biological
factor (e.g., chlorophyll-a). This study concludes that the upwelling
region off the ECPM is potentially an important source of atmospheric
isoprene and monoterpenes.