Nonclassical multiphoton have attracted extensive attention to serve as entangled resources for quantum information technology. Here, the continuous‐mode hyper‐entangled W‐class triphotons are theoretically generated through spontaneous six‐wave mixing (SSWM) in 85Rb. In nonlinear optical response, Zeeman sub‐states are high‐dimensionally quantized by polarized dressing. High‐dimensional entanglement is structured via atomic non‐Hermitian nature. Through linear optical response, the temporal correlations are shaped via diverse polarized dressing. SSWM‐based triphoton is a genuine triphoton possessing non‐Gaussian tripartite entanglement. The high production rate is due to co‐action of three strong input fields, electromagnetically induced transparency (EIT) protection, and slow light effect. Non‐Hermitian nature endows the system with sensitive adjustability around exceptional points (EP). Eventually, the results demonstrate multiple SSWMs causing oscillations with multiple periods in three‐photon temporal correlations for the nonlinear region, build a high‐dimensional three‐body entangled quantum network and transform multifarious profiles of the three‐photon temporal correlations for the linear region. Especially, both high‐dimensional and hyper entanglements are obtained, contributing to high quantum information capacity. Further, the system is switched among multiple states when non‐Hermitian nature is manipulated by polarized dressing. The research opens a broad prospect for generating the hyper‐entangled multiphoton with potential application in adjustable quantum networks of high information capacity.