In
this study, we established the energy alignment of the Ca(CF3SO3)2-doped poly(ethylene oxide)/poly(3-hexylthiophene-2,5-diyl),
i.e., CaTf
2-PEO/P3HT, heterojunction.
The concentration polarization of ions could dynamically adjust the
energy level of the PEO complex, similar to light-emitting electrochemical
cells (LECs). When bias is loaded in the orientation from CaTf
2-PEO-PEO to P3HT, the charge diffusions appears
and the internal electric field (E
in)
is generated. Simultaneously, the accumulation of the ions also induces
the interface stress which could be released partially after some
ions are doped into the P3HT layer. The interface polarization and
doping are found to be modulated by the external field under various
loading rates. These two effects interact together thereby determining
the size of E
in and resulting in the negative
differential resistance (NDR) phenomenon. The NDR peak increases with
the sweeping times under conditions of slow loading rates, while it
decreases under conditions of extremely high loading rates. The responses
of the system and the related weight modifications of the NDR peaks
are tested using a train of triangular pulses with fixed amplitude
and varied loading rates. The weight obtained by calculating the 40th
response is invariably positive for low loading rates, while it potentiates
under low frequency stimulations but depresses under high frequency
stimulations, i.e., frequency selectivity, for the conditions of very
high loading rates. Our results reveal that the organic electrolyte/semiconductor
heterojunction could be a simple system for analyzing and computing
complicated signals in high resolutions.