a b s t r a c tWe examined and compared PM 2.5 concentrations in urban and the surrounding regions, and further investigated the impact of urbanization on urban PM 2.5 concentrations at the Chinese prefectures.Annual PM 2.5 concentrations in most prefectures were greater than 10 mg/m 3 , the air quality guideline of the World Health Organization. Those prefectures were mainly distributed along the east coast and southeast of Sichuan province; The urban PM 2.5 concentrations (Urban PM2:5 ) in 85 cities were greater than (>10 mg/m 3 ) those in the surrounding area. Those cities were mainly located in the BeijingeSichuan and ShanghaieGuangxi belts. In addition, Urban PM2:5 was less than (<0 mg/m 3 ) that in surrounding areas in only 41 prefectures, which were located in western China or nearby mega cities; Significant positive correlations were found between Urban PM2:5 and urban population (R 2 ¼ 0.99, P < 0.05), and between Urban PM2:5 and urban second industry fraction (R 2 ¼ 0.71, P < 0.05), suggesting that urbanization had considerable impact on PM 2.5 concentrations.