The Riemann-Hilbert approach to studying solutions of supergravity theories allows us to associate spacetime independent monodromy matrices (matrices in the Geroch group) with solutions that effectively only depend on two spacetime coordinates. This offers insights into symmetries of supergravity theories, and in the classification of their solutions. In this paper, we initiate a systematic study of monodromy matrices for multicenter solutions of five-dimensional U(1) 3 supergravity. We obtain monodromy matrices for a class of collinear Bena-Warner bubbling geometries. We show that for this class of solutions, monodromy matrices in the vector representation of SO(4,4) have only simple poles with residues of rank two and nilpotency degree two. These properties strongly suggest that an inverse scattering construction along the lines of [arXiv:1311.7018 [hepth]] can be given for this class of solutions, though it is not attempted in this work. Along the way, we clarify a technical point in the existing literature: we show that the so-called "spectral flow transformations" of Bena, Bobev, and Warner are precisely a class of Harrison transformations when restricted to the situation of two commuting Killing symmetries in five-dimensions.