Speciation, Mobility and Potential Toxicity of Metals (Cr, Co, Cu and Mn) in Soil Samples From Dumpsites in Kano Metropolis

Abstract

Soil pollution by heavy metals is a global environmental problem. The need to keep the environment clean is increasingly becoming a global concern. Heavy metals are one group of pollutants that are widespread in our environment. They tend to persist indefinitely once they enter the soil. Their mobility and toxicity depend on their forms and oxidation states in the soil. This research presents the speciation, mobility and potential toxicity of Cr, Co, Cu and Mn in soils from some dumpsites in Kano, using a six-step sequential extraction method and AAS analysis. The results revealed the pH of the soils to range from 6.20-7.80. Percentage composition of clay and organic matter ranged from 6.00-16.58 % and 0.48- 4.30 % respectively. The results showed that the metals are bioavailable at different forms evident from their distribution pattern in the different fractions and therefore the soils should not be used for cultivation to avoid the metals getting into the food chain. The mobility factor values ranging between 14.38 % and 61.48 % for dry season; 15.63 % and 74.74 % for rainy season showed the metals to be very mobile especially Co, Cu, and Mn. This could lead to potential pollution of the agricultural produce and ground water in this area and hence have toxic effects on human lives. This result can serve as a guide to researchers on the appropriate method to reclaim the soils in this area based on the pattern of distribution of the metals in different geochemical phases.

Environmental Geochemical Investigation of the Geogenic Pollution Potential of Bida Formation, Northern Bida Basin Nigeria

“…It, therefore, shows that even if the total concentration of each of the elements is passed onto the residual soils as discrete grains through physical weathering, they are unlikely to pose serious geogenic environmental pollution problems. Although most existing environmental risk assessment indices use the total concentration of contaminant elements, a knowledge of the easily solubilized or biogeoaccessible fraction is key to understanding the scale of the problem (Adamu and Olaleye, 2022;Waziri, 2013;Ullrich et al, 1999). Because the metals are not soluble and they partition strongly to the solid phase, they will not be readily available for uptake by plant roots, or will not be directly toxic to soil biota.…”

“…Metals occur widely in the natural environment and are observed in sedimentary rocks, soils, water, and organic matter (Davies, 1987). The pollution of soil with metals is a global environmental problem (Adamu and Olaleye, 2022). Weathering of rocks and subsequent leaching and erosion are among the sources of environmental pollution of geogenic nature (Grba et al, 2015;Wang et al, 2023).…”

Sustainable remediation of chromium-contaminated soils: boosting radish growth with deashed biochar and strigolactone

“…Cr's environmental circumstances involve dynamic processes influenced by redox reactions, precipitation dissolution, and adsorption. Certain Cr forms in soil, especially the water-soluble and ion-exchange states, are highly mobile and bioavailable [9]. While Cr is essential for plant growth, excessive concentrations can hinder development, affecting nutrient uptake and photosynthesis, causing lipid peroxidation, and altering antioxidant activity.…”