Speciation of the volatile organic compounds (VOCs) in solventborne aerosol coatings by solid phase microextraction-gas chromatography

Censullo, Albert C.; Jones, Dane R.; Wills, Max T.

doi:10.1007/bf02697922

Cited by 5 publications

(2 citation statements)

References 3 publications

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“…It is a compound identifiable by an unpleasant smell with a potential to form carcinogenic nitrosamines in the air after emitted for a certain period. The use of such a coating on a structure for an extended period risks exposing people to the emitting VOC (Censullo et al, 2003;Dinh et al, 2016;Eklund & Nelson, 1995). Hence, researchers have developed a variety of techniques to measure the amount of VOCs emitted by coatings and established the corresponding standards to decrease the risk of detrimental health effects on humans.…”

Section: Journal Of Sustainabilitymentioning

confidence: 99%

ASSESSMENT OF CORROSION EFFICIENCY AND VOLATILE ORGANIC COMPOUNDS CONTENT FOR A GREEN COATING WITH NOVEL ADDITIVE OF Leucaena leucocephala

Kamaruzzaman¹,

Fekeri²,

Shaifudin³

et al. 2021

JSSM

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A large number of anti-corrosion coatings containing volatile solvents with aliphatic hydrocarbons, formaldehyde and benzene are produced annually with the risk of releasing harmful volatile organic compounds (VOCs) into the air. In this study, a commercial coating product for protecting steel is compared with the newly formulated green coating for the quantification of VOC content. The comparison was executed using the mass difference method following ASTM D2369-03. The extract and formulated coating were also subjected to optical, electrochemical and morphological studies, ie, Fourier Transform Infrared (FTIR) Spectroscopy, Ultraviolet-Visible (UV-Vis) Spectroscopy, Electrochemical Impedance Spectroscopy (EIS) and Scanning Electron Microscope/Energy Dispersive X-Ray (SEM/EDX). Based on the extract characterization, functional groups of hydroxyl, carboxylic acid and carbonyl with wavenumbers of 3350.cm -1 , 2947.23 cm -1 and 1053.13 cm -1 , respectively were identified. Also, coating with 3 wt.% of Leucaena leucocephala leaves extract (LLE), P2 showed a consistent optimum performance in reducing corrosion until the 40 th day with a rate of 3.14 x10 -3 mm/year. The P2 sample was later subjected to VOCs content analysis, and the outcome displayed a lower VOCs content of 345.40 g/L compared to a commercial product, which fulfilled the standard requirement for low-VOC paint by the Environmental Protection Agency (EPA). Hence, it can be concluded that the developed green anticorrosion coating possessed low VOCs content with excellent abilities in protecting steel exposed to an aggressive environment.

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Section: Journal Of Sustainabilitymentioning

confidence: 99%

ASSESSMENT OF CORROSION EFFICIENCY AND VOLATILE ORGANIC COMPOUNDS CONTENT FOR A GREEN COATING WITH NOVEL ADDITIVE OF Leucaena leucocephala

Kamaruzzaman¹,

Fekeri²,

Shaifudin³

et al. 2021

JSSM

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“…In this study, VOCs in water-based paints could be quantified by a simple method using only liquidliquid distribution. There have been studies on the analysis of VOCs in water-based paints 9,13,14) but no studies on the simultaneous analysis of 12 VOCs that differ in polarity from polar substances to nonpolar substances such as TMPDIB by GC/MS. Therefore, this method is applicable to the measurement of VOCs used in water-based paints.…”

Section: Analysis Of Commercially Available Productsmentioning

confidence: 99%

Volatile Organic Compound (VOC) Analysis and Anti-VOC Measures in Water-based Paints

Nakashima

Nakajima

Takagi

et al. 2007

JOURNAL OF HEALTH SCIENCE

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We developed an analytical method for volatile organic compounds (VOCs) used as film-forming agents or anti-freeze agents in water-based paints by flame ionization detection (FID-GC) and gas chromatography mass spectrometry (GC/MS). Twelve VOC components were separated using 2 types of column that differ in polarity. In addition, a pretreatment method by ethyl acetate-water partition was evaluated, and a survey of the use of VOCs in commercially available water-based paints was performed. For indoor paints, the anti-VOC measures included changes from VOC solvents to semi-VOC (SVOC) solvents such as those from 2,2,4-trimethyl-1,3-pentanediolmonoisobutyrate (TMPMIB) to 2,2,4-trimethyl-1,3-pentanediol diisobutyrate and from ethylene glycol (EG) to triethylene glycol. However, in multipurpose paints for both indoor and outdoor use, VOCs such as EG, TMPMIB, diethyleneglycol dibutyl ether, and diethyleneglycol monobutyl ether were detected. Since these products may be also used for indoor painting, indications of VOC components and caution for use on products are necessary.

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Activity and selectivity of Co(Ni)Mo sulfides supported on MgO, Al2O3, ZrO2, TiO2, MCM-41 and activated carbon in parallel hydrodeoxygenation of octanoic acid and hydrodesulfurization of 1-benzothiophene

Kaluža

Karban

Gulková

2019

Reac Kinet Mech Cat

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Speciation of the volatile organic compounds (VOCs) in solventborne aerosol coatings by solid phase microextraction-gas chromatography

Cited by 5 publications

References 3 publications

ASSESSMENT OF CORROSION EFFICIENCY AND VOLATILE ORGANIC COMPOUNDS CONTENT FOR A GREEN COATING WITH NOVEL ADDITIVE OF Leucaena leucocephala

ASSESSMENT OF CORROSION EFFICIENCY AND VOLATILE ORGANIC COMPOUNDS CONTENT FOR A GREEN COATING WITH NOVEL ADDITIVE OF Leucaena leucocephala

Volatile Organic Compound (VOC) Analysis and Anti-VOC Measures in Water-based Paints

Activity and selectivity of Co(Ni)Mo sulfides supported on MgO, Al2O3, ZrO2, TiO2, MCM-41 and activated carbon in parallel hydrodeoxygenation of octanoic acid and hydrodesulfurization of 1-benzothiophene

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