2013
DOI: 10.1155/2013/106357
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Speciation Studies of Diorganotin(IV) Complexes with 3,3‐Bis(1‐methylimidazol‐2‐yl)propionate—Displacement Reaction by DNA Constituents

Abstract: The interaction of 3,3-bis(1-methylimidazol-2-yl)propionate (BIMP) with dimethyltin(IV) dichloride (DMT), dibutyltin(IV) dichloride (DBT), and diphenyltin(IV) dichloride (DPT) is investigated at 25°C and 0.1 M ionic strength in water for dimethyltin(IV), and in a 50% dioxane-water mixture for dibutyltin(IV) and diphenyltin(IV). The stepwise formation constants of the 1 : 1 and 1 : 2 complexes formed in solution are calculated from potentiometric measurements using the nonlinear least-square program MINIQUAD-75… Show more

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