Specific recognition of toxic allyl alcohol by pore-functionalized metal–organic frameworks

Desai, Aamod V.; Sharma, Shivani; Roy, Arkendu; Shirolkar, Mandar M.; Ghosh, Sujit K.

doi:10.1039/c9me00133f

Cited by 8 publications

(2 citation statements)

References 81 publications

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“…The authors reported a clear preference for adsorption of Q over QH 2 by the MOF. In a more recent investigation, we developed a sensor for allyl alcohol, a highly toxic and volatile analyte regarded by the EPA as a priority pollutant [72] . Two MOFs with molecular formula ([In(L)(Cl) 3 ] n ( 9 ) and [Mn 2 (L) 2 (Cl) 4 ] n , ( 10 ) (L=tris(4‐(1H‐imidazol‐1‐yl)phenyl)amine) were fabricated that were tethered with metal‐chloride functional groups as well as a highly conjugated tripodal ligand.…”

Section: Neutral N‐donor Linker‐based Mofs Displaying Molecular Recognition Via Different Signal Transduction Pathwaymentioning

confidence: 99%

Neutral Nitrogen Donor Ligand‐based MOFs for Sensing Applications

Sharma

Dutta

Dam

et al. 2021

Chemistry An Asian Journal

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Neutral nitrogen donor (N‐donor) ligand‐based MOFs, with their enticing features inclusive of facile synthesis, labile metal‐ligand bond, framework flexibility, atomic level tunability renders them appealing in molecular recognition‐based studies. Intriguingly, the flexibility in such systems (owing to weaker metal‐nitrogen bonds) promote maximization of host‐analyte interactions, which is critical for the manifestation of a signaling response. Such host‐analyte interactions can be tapped by discerning any change in the physical properties associated with the system, such as optical, fluorometric, chemiresistive, magnetic, dielectric constant, mass. This minireview presents a brief discussion on the various types of signal transduction pathways unveiled hitherto using neutral N‐donor ligand‐based MOFs and the fundamental insight into the signal‘s origin. Moreover, an elaborate compilation of the recent examples in this field has been presented. Also, the untapped prospects have been highlighted, which may serve as a beacon to drive future research.

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Section: Neutral N‐donor Linker‐based Mofs Displaying Molecular Recognition Via Different Signal Transduction Pathwaymentioning

confidence: 99%

Neutral Nitrogen Donor Ligand‐based MOFs for Sensing Applications

Sharma

Dutta

Dam

et al. 2021

Chemistry An Asian Journal

Self Cite

View full text Add to dashboard Cite

show abstract

“…In 2021, Chand et al 29 prepared a luminescent sensor (Co-MOF) that can selectively detect Al( iii ) by a mixed-ligand synthesis approach. Moreover, there are a few reports on the application of luminescent MOFs in the detection of toxic and harmful organic small molecules (allyl alcohol, 30 acetone, 31 acetylacetone, 32 pyridine, toluene, etc .). Pyridine and its derivatives can be used as solvents and intermediates in the production of pesticides, dyes, additives, pharmaceuticals, etc ., and are important raw materials in chemical production.…”

Section: Introductionmentioning

confidence: 99%