Modern web wants the data to be in Resource Description Framework (RDF) format, a machine-readable form that is easy to share and reuse data without human intervention. However, most of the information is still available in relational form. The existing conventional methods transform the data from RDB to RDF using instance-level mapping, which has not yielded the expected results because of poor mapping. Hence, in this paper, a novel schema-based RDB-RDF mapping method (relational database to Resource Description Framework) is proposed, which is an improvised version for transforming the relational database into the Resource Description Framework. It provides both data materialization and on-demand mapping. RDB-RDF reduces the data retrieval time for nonprimary key search by using schema-level mapping. The resultant mapped RDF graph presents the relational database in a conceptual schema and maintains the instance triples as data graph. This mechanism is known as data materialization, which suits well for the static dataset. To get the data in a dynamic environment, query translation (on-demand mapping) is best instead of whole data conversion. The proposed approach directly converts the SPARQL query into SQL query using the mapping descriptions available in the proposed system. The mapping description is the key component of this proposed system which is responsible for quick data retrieval and query translation. Join expression introduced in the proposed RDB-RDF mapping method efficiently handles all complex operations with primary and foreign keys. Experimental evaluation is done on the graphics designer database. It is observed from the result that the proposed schema-based RDB-RDF mapping method accomplishes more comprehensible mapping than conventional methods by dissolving structural and operational differences.