Spectral characterization, optical band gap calculations and DNA binding of some binuclear Schiff-base metal complexes derived from 2-amino-ethanoic acid and acetylacetone

Hussien, Mostafa A.; Nawar, Nagwa; Radwan, Fatima M.; Hosny, Nasser Mohammed

doi:10.1016/j.molstruc.2014.09.071

Cited by 33 publications

(7 citation statements)

References 29 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Where " T " is the transmittance (%), "α" is the absorption coefficient, "d" is thickness of thin films; the factor (A) depends on the transition probability assumed to be as respectively (Table 1). The obtained gaps energy values are simulated to results reported in the literature by M. A. Hussien et al [33][34], this study findings indicate that these complexes have the characteristics of semi-conductors. Moreover, the values of energy gaps belong to the range of highly efficient photovoltaic materials energies.…”

Section: Surface Morphological Studiessupporting

confidence: 77%

See 1 more Smart Citation

SILAR Deposition of Ni(bpy)₃X: {X = (NCS)₂, (Fe(CN)₅NO), and (Ag(CN)₂)₂} Thin Films on Glass Substrates

Bendjeffal

Guibedj

Chastanet

et al. 2016

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-

View full text Add to dashboard Cite

HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L'archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d'enseignement et de recherche français ou étrangers, des laboratoires publics ou privés. SILAR deposition of Ni(bpy)3X : { X = (NCS)2, (Fe(CN)5NO) and(Ag(CN)2)2} thin films on glass substrates

show abstract

Section: Surface Morphological Studiessupporting

confidence: 77%

“…Moreover, the values of energy gaps belong to the range of highly efficient photovoltaic materials energies. Hence, the studied complexes can be considered as potential materials for many optical applications [30][31][32][33][34].…”

Section: Surface Morphological Studiesmentioning

confidence: 99%

SILAR Deposition of Ni(bpy)₃X: {X = (NCS)₂, (Fe(CN)₅NO), and (Ag(CN)₂)₂} Thin Films on Glass Substrates

Bendjeffal

Guibedj

Chastanet

et al. 2016

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-

View full text Add to dashboard Cite

show abstract

“…The growing demand for the synthesis of organic and inorganic compounds has attracted the involvement of various solvent molecules in many industries such as pharmaceuticals, paints and coatings, and dyes, etc. , These small solvent molecules possess harmful effects with respect to environment, health hazards, and security issues. One such solvent is acetylacetone, which has been extensively used in industry due to its diverse roles as (i) an additive in paints, coatings, lubricants, and gasoline, (ii) a ligand precursor and an intermediate for organic synthesis, (iii) an analytical extraction and separation reagent, (iv) a modifier or chelating agent in sol–gel synthesis, and (v) an absorbent to remove formaldehyde. − Owing to its excessive use, it can cause health problems such as skin and eye irritation, dizziness, headache, insensibility, and nausea upon inhalation. Moreover, it is volatile in nature for which it can act as a combustible and an explosive upon unrestricted exposure in air, causing environmental pollution.…”

Section: Introductionmentioning

confidence: 99%

Polar Sulfone-Functionalized Oxygen-Rich Metal–Organic Frameworks for Highly Selective CO₂ Capture and Sensitive Detection of Acetylacetone at ppb Level

Chakraborty

Das

Mandal

2020

ACS Appl. Mater. Interfaces

View full text Add to dashboard Cite

A rational combination of an oxygen-rich pyridyl substituted tetrapodal ligand, tetrakis(4-pyridyloxymethylene)methane (TPOM), and a polar sulfone-functionalized conjugated bent dicarboxylate linker, dibenzothiophene-5,5′-dioxide-3,7-dicarboxylic acid (H2(3,7-DBTDC)), with d10 metal centers, Zn(II) and Cd(II), has led to the construction of two new three-dimensional (3D) metal–organic frameworks,{[Zn2(TPOM)(3,7-DBTDC)2]·7H2O·DMA} n (1) and {[Cd2(TPOM)(3,7-DBTDC)2]·6H2O·3DMF} n (2). Single-crystal X-ray analysis indicates that 1 is a 3D framework with a dinuclear repeating unit having two different Zn(II) centers (tetrahedral and square pyramidal) and 2 is a 3D framework comprised of a dinuclear repeating unit with one crystallographically independent distorted pentagonal bipyramidal Cd(II) coordinated to chelating/bridging carboxylates and nitrogen atoms of the TPOM ligand. In both cases, the pores are aligned with oxygen atoms of the TPOM ligand and decorated with polar sulfone moieties. On the basis of the stability established by thermogravimetric analysis and powder X-ray diffraction (PXRD) and the presence of large solvent accessible voids (25.4% for 1 and 40.6% for 2), gas sorption studies of different gases (N2, CO2, and CH4) and water vapor have been explored for both 1 and 2. The CO2 sorption isotherm depicts type I isotherm with an uptake of 93.6 cm3 g–1 (for 1) and 100.6 cm3 g–1 (for 2) at 195 K. Additionally, sorption of CO2 is highly selective over that of N2 and CH4 for both 1 and 2 due to the strong quadrupolar interactions between sulfone moieties and CO2 molecules. Configurational bias Monte Carlo (CBMC) molecular simulation has further justified the highly selective CO2 capture. On the other hand, the luminescence nature of 1 and 2 has been employed for highly selective detection of acetylacetone in aqueous methanol with a limit of 59 ppb in 1 and 66 ppb in 2, which are among the best reported values so far in the literature. The Stern–Volmer plots, spectral overlap, density functional theory calculations, CBMC simulation, and time-resolved lifetime measurements have been utilized for an extensive mechanistic study. The exclusive selectivity for acetylacetone in 1 and 2 have been confirmed by competitive selectivity test. Both exhibited good recyclability and stability after sensing experiments analyzed by fluorescence, PXRD, and field emission scanning electron microscopy studies.

show abstract

“…Acetylacetone is widely employed because of its important industrial applications,s uch as its use as an intermediate and precursor ligand for organics ynthesis; [1][2][3][4] analytical reagent for extraction and separation;c helating agent or modifier in the sol-gel process; [5][6][7][8] solventf or non-aqueous redox-flow-batteries [9] and as an ovel absorber for selectiver emoval of formaldehyde. [10] However,a cetylacetone, as at oxic chemical, severely harms human health,r esulting in dizziness, nausea, andunconsciousnessw hen inhaled, ingested, or absorbedb yt he skin.…”

mentioning

confidence: 99%

A Sensitive Luminescent Acetylacetone Probe Based on Zn‐MOF with Six‐Fold Interpenetration

Kang

Cheng

et al. 2017

Chemistry A European J

View full text Add to dashboard Cite

A novel metal-organic framework {[Zn(XL) ](ClO ) ⋅6 H O} (XL=N,N'-bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxdiimide bi(1,2,4-triazole)) was synthesized and structurally characterized, presenting the first example of six-fold interpenetrating 3 D framework with the topology type of sqc6, which displays high thermostability and solvent stability. Additionally, the luminescence investigations reveal that this MOF can sensitively and selectively detect acetylacetone with a detection limit of 1.72 ppm. More importantly, it is rather rare for an MOF-based luminescence probe to serve as a sensor to effectively detect acetylacetone.

show abstract

Spectral characterization, optical band gap calculations and DNA binding of some binuclear Schiff-base metal complexes derived from 2-amino-ethanoic acid and acetylacetone

Cited by 33 publications

References 29 publications

SILAR Deposition of Ni(bpy)₃X: {X = (NCS)₂, (Fe(CN)₅NO), and (Ag(CN)₂)₂} Thin Films on Glass Substrates

SILAR Deposition of Ni(bpy)₃X: {X = (NCS)₂, (Fe(CN)₅NO), and (Ag(CN)₂)₂} Thin Films on Glass Substrates

Polar Sulfone-Functionalized Oxygen-Rich Metal–Organic Frameworks for Highly Selective CO₂ Capture and Sensitive Detection of Acetylacetone at ppb Level

A Sensitive Luminescent Acetylacetone Probe Based on Zn‐MOF with Six‐Fold Interpenetration

Contact Info

Product

Resources

About

Spectral characterization, optical band gap calculations and DNA binding of some binuclear Schiff-base metal complexes derived from 2-amino-ethanoic acid and acetylacetone

Cited by 33 publications

References 29 publications

SILAR Deposition of Ni(bpy)3X: {X = (NCS)2, (Fe(CN)5NO), and (Ag(CN)2)2} Thin Films on Glass Substrates

SILAR Deposition of Ni(bpy)3X: {X = (NCS)2, (Fe(CN)5NO), and (Ag(CN)2)2} Thin Films on Glass Substrates

Polar Sulfone-Functionalized Oxygen-Rich Metal–Organic Frameworks for Highly Selective CO2 Capture and Sensitive Detection of Acetylacetone at ppb Level

A Sensitive Luminescent Acetylacetone Probe Based on Zn‐MOF with Six‐Fold Interpenetration

Contact Info

Product

Resources

About

SILAR Deposition of Ni(bpy)₃X: {X = (NCS)₂, (Fe(CN)₅NO), and (Ag(CN)₂)₂} Thin Films on Glass Substrates

SILAR Deposition of Ni(bpy)₃X: {X = (NCS)₂, (Fe(CN)₅NO), and (Ag(CN)₂)₂} Thin Films on Glass Substrates

Polar Sulfone-Functionalized Oxygen-Rich Metal–Organic Frameworks for Highly Selective CO₂ Capture and Sensitive Detection of Acetylacetone at ppb Level