2014
DOI: 10.1140/epjd/e2014-50071-1
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Spectral investigation of doubly ionized rubidium (Rb III) from relativistic Hartree-Fock calculations

Abstract: Abstract. Radiative decay parameters (oscillator strengths, transition probabilities) for spectral lines in doubly ionized rubidium (Rb III) are reported for the first time. They have been obtained using a pseudorelativistic Hartree-Fock (HFR) model including a large amount of intravalence correlation as well as corepolarization effects. The spectroscopic data listed in the present paper cover a wide range of wavelengths from extreme ultraviolet to near infrared.

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Cited by 3 publications
(3 citation statements)
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“…The upper limit derived from the non-detection of very weak predicted Sc III and V III lines are next to meaningless for both stars. Zhang et al (2014) provided atomic data for Rb III. However, because these lines have never been observed, their positions are likely not accurate.…”
Section: Discussionmentioning
confidence: 99%
“…The upper limit derived from the non-detection of very weak predicted Sc III and V III lines are next to meaningless for both stars. Zhang et al (2014) provided atomic data for Rb III. However, because these lines have never been observed, their positions are likely not accurate.…”
Section: Discussionmentioning
confidence: 99%
“…In order to fill in this gap, in the present paper, we report on calculations of oscillator strengths and transition probabilities in this ion performed using the HFR approach including corepolarization effects. This work is an extension of our recent investigations of the fifth row elements Rb III (Zhang et al 2014), Y II, Y III (Biémont et al 2011), Zr II (Malcheva et al 2006), Nb I (Malcheva et al 2011), Nb II, Nb III (Nilsson et al 2010), Mo II , Lundberg et al 2010, Jiang et al 2012, Tc II (Palmeri et al 2007), Ru I (Fivet et al 2009), Ru II, RuIII (Palmeri et al 2009), Rh II (Quinet et al 2011(Quinet et al , 2012, Rh III (Zhang et al 2013a), Pd I (Xu et al 2006), Pd III (Zhang et al 2013a), Ag II (Biémont et al 2005, Campos et al 2005, Ag III (Zhang et al 2013a), Sn I (Zhang et al 2008(Zhang et al , 2009(Zhang et al , 2010, Sb I (Hartman et al 2010), Te II and Te III (Zhang et al 2013b).…”
Section: Introductionmentioning
confidence: 62%
“…During the past 5 years, we notably focused our work on the particular cases of Rb III (Z = 37), Mo III (Z = 42), Rh III (Z = 45), Pd III (Z = 46), Ag III (Z = 47), and Te III (Z = 52) for which no (or very few) radiative rates were available in the literature. For all these ions, the HFR + CPOL + CPEN method has been combined to a semi-empirical adjustment of radial parameters minimizing the differences between calculated energy levels and available experimental values to compute transition probabilities and oscillator strengths for a large number of spectral lines [69][70][71][72]. Because of the lack of radiative lifetime measurements, the quality of our calculations could only be estimated from isoelectronic comparisons, in particular from results we had formerly published in Nb II (isoelectronic of Mo III) [73], in Ru II (isoelectronic of Rh III) [74], and in Rh II (isoelectronic of Pd III) [75], for which similar HFR + CPOL + CPEN models revealed a very good agreement (generally within 10%) with accurate radiative lifetimes measured by means of the time-resolved laser-induced fluorescence technique.…”
Section: Fifth Row Elementsmentioning
confidence: 99%