A cavity ring-down (CRD) setup equipped with a pulsed broadband light source (480 nm ≤ λ ≤ 650 nm) and a multichannel detection system (temporal gate width Δτ = 20 ns) is used to simultaneously record the optical loss spectrum of an intra-cavity CaF2 sample and its changes upon transverse ArF laser irradiation at 193 nm. The CRD setup with mirrors of high reflectivity (R > 99.93%) allows to register loss changes of 5 × 10(-5) with a spectral resolution of 0.3 nm in less than 2 min.