Spectres d'absorption dans l'infrarouge lointain des chlorures de cobalt et de nickel hexahydrates

Vergnat, P.; Vergnat-Grandjean, D.; Hadni, A.

doi:10.1016/0584-8539(74)80185-6

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1980

1988

Publication Types

Select...

Article4

Book1

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 5 publications

References 12 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Raman and infrared spectra of transition metal halide hexahydrates

Agulló-Rueda

Calleja

Martini³

et al. 1987

J Raman Spectroscopy

View full text Add to dashboard Cite

The Raman and infrared spectra of NiC12.6H20, NiC1,-6Dz0, CoCl,.6H,O, CoC1,-6Dz0 and CoBr,-6H,O single crystals have been measured in the range 3600-30 cm-' (Raman) and 3800-400 cm-' (IR). The water internal modes have been best assigned for NiC12.6H,0, including Fermi resonance effects. The corresponding Raman intensities have been interpreted in terms of the free molecule Raman tensors. Among the lattice vibrations, the metal halide and metal-water stretchings, and also the librations of the MX2.4H20 octahedra, have been identified and assigned.

show abstract