Spectrophotometric determination of the perchlorate ion

Trautwein, Norman L.; Guyon, John C.

doi:10.1021/ac60259a042

Cited by 10 publications

(1 citation statement)

References 9 publications

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“…24 The modification was used to destroy hypochlorite in the sample as described in ref 23. The procedure used for determination of perchlorate was a modified form of that given by Trautwein and Guy on. 25 The modification was used to destroy hypochlorite, chlorite, and chlorate in the sample as described in ref 23.…”

Section: Methodsmentioning

confidence: 99%

Photochemically induced reactions in a chlorine-ozone system at -10.5 and 0.0.deg.

Davidson¹,

Williams²

1973

J. Phys. Chem.

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The reactions of the system were induced by light of wavelength 365-366.5 µ. The products of the system were removed from the reactor and dissolved in water. The water solution was tested for the ionic chlorine species chloride, hypochlorite, chlorite, chlorate, and perchlorate. Dichlorine heptoxide was found to be the only stable chlorine oxide product of the reaction. The formation of dichlorine heptoxide was studied with respect to the light intensity, reactant concentration, presence of diluents, temperature, and total pressure. The observed data and information already in the literature were used to develop a reaction mechanism which was based on the formation of a proposed chlorine atom-ozone complex. Analysis of the mechanism showed that it adhered to the observed data and the use of certain known rate constants allowed the attainment of several rate constants concerning the formation of the chlorine atom-ozone complex.

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Section: Methodsmentioning

confidence: 99%

Photochemically induced reactions in a chlorine-ozone system at -10.5 and 0.0.deg.

Davidson¹,

Williams²

1973

J. Phys. Chem.

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Activation and transfer of oxygen. VI. The influence of hydrochloric acid on the autoxidation of dihydroalloxazines

Mager

Berends

1972

Recl. Trav. Chim. Pays‐Bas

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Autoxidative processes in HCI may be influenced by reactions of the organic peroxy intermediates, or of H,O,, with the medium. These reactions with HCI led to the evolution of O2 and also of CI, under certain conditions. The question whether HCI is oxidized by an organic peroxy intermediate or by H,O, could be answered.Organic compounds may be chlorinated by H,O,-HCI in high yields. The experiments strongly support the idea that aromatic chlorination is then effected by the species HOCl and/or HOOCI which are produced in situ.

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Oximes as spectrophotometric reagents—a review

Singh

Garg

1979

Talanta

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Spectrophotometric determination of the perchlorate ion

Cited by 10 publications

References 9 publications

Photochemically induced reactions in a chlorine-ozone system at -10.5 and 0.0.deg.

Photochemically induced reactions in a chlorine-ozone system at -10.5 and 0.0.deg.

Activation and transfer of oxygen. VI. The influence of hydrochloric acid on the autoxidation of dihydroalloxazines

Oximes as spectrophotometric reagents—a review

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