2005
DOI: 10.26850/1678-4618eqj.v30.3.2005.p63-71
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Spectrophotometric study of iron oxidation in the iron(II)/thiocyanate/acetone system and some analytical applications

Abstract: The possibility of using thiocyanate to determine iron(II) and/or iron(III) in water-acetone mixturehas been re-examined as part of a systematic and comparative study involving metallic complexes ofpseudohalide ligands. Some parameters that affect the complete oxidation of the ferrous cations, theirsubsequent complexation and the system stability have been studied to optimize the experimental conditions.Our results show the viability and potentiality of this simply methodology as an alternative analytical proc… Show more

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