The new bifunctional crystal, Yb-doped RbTiOPO4 or Yb:RTP, codoped with Nb for charge compensation, combines the lasing properties of the Yb-ion with the nonlinear properties of the well-known orthorhombic crystal RTP [1]. It is interesting for the development of compact all-solid-state laser sources in the green, by self-frequency doubling. The Yb-ion possesses a number of advantages over Nd: Longer energy-storage time and smaller quantum defect, pumping by the optically more robust InGaAs laser diodes operating in the 900-1000 nm range, relatively simple two-manifold structure without absorption losses at the second harmonic, and broader absorption and emission lines.Lasing of Yb3+ has been demonstated only in 6 acentric hosts, XAl3(BO3)4 and XCa4O(BO3)3 where X=Y or Gd, LiNbO3 and KGd(PO3)4, but the attraction of nonlinear materials belonging to the KTiOPO4 (KTP) family is related to