Spectroscopic data, spin-orbit functions, and revised analysis of strong perturbative interactions for the<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:mi>A</mml:mi><mml:msup><mml:mi> </mml:mi><mml:mrow><mml:mn>1</mml:mn></mml:mrow></mml:msup><mml:msup><mml:mi>Σ</mml:mi><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>and<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:mi>b</mml:mi><mml:msup><mml:mi> <

Docenko, O.; Tamanis, M.; Ferber, R.; Bergeman, T.; Kotochigova, Svetlana; Stolyarov, A. V.; Nogueira, Andreia de Faria; Fellows, C. E.

doi:10.1103/physreva.81.042511

Cited by 60 publications

(57 citation statements)

References 61 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…For instance, the shape of the A 1 Σ + ub 3 Π u and B 1 Π u -b 3 Π u SO coupling functions as well as b 3 Π u SO splitting functions corresponding to the second dissociation limit (see figures 1a,b and 2a) looks like the inharmonic interatomic potential with the minimum which is approximately 2/3 of the relevant atomic value. The similar behavior of the A − b, B − b and b − b matrix elements is observed for heteronuclear alkali diatomics [23,24,25,26] as well. At the same time, the single configuration properties of the 2 1,3 Π u and 1 1,3 ∆ u states of Cs 2 converging to the third dissociation limit are confirmed by the almost R-independent behavior of the relevant SO matrix elements closed to their asymptotic atomic value ξ 5 2 D Cs (see figure 3a).…”

Section: The Spin-orbit Coupling Matrix Elementssupporting

confidence: 77%

See 1 more Smart Citation

Theoretical study of spin–orbit and Coriolis coupling among the low-lying states of Rb2 and Cs2

2015

View full text Add to dashboard Cite

Section: The Spin-orbit Coupling Matrix Elementssupporting

confidence: 77%

“…We implemented here slightly modified computational procedure which has been successfully applied to the several heteronuclear molecules such as NaRb [23], NaCs [24], KCs [25] and RbCs [26].…”

Section: Computational Approachmentioning

confidence: 99%

Theoretical study of spin–orbit and Coriolis coupling among the low-lying states of Rb2 and Cs2

2015

View full text Add to dashboard Cite

“…It is well-known that due to configuration mixing the SO couplings vary with the internuclear distance and can be reduced or enhanced typically by 30-50% compared to the atomic values. Examples can be found for instance in spectroscopic studies of RbCs [81], KCs [60], or in quantum chemistry studies of Sr 2 [82], SrYb [83] or Rb 2 [84]. It is beyond the goal of this paper to compute the R-dependence of the SO coupling in RbSr.…”

Section: Higher Excited Statesmentioning

confidence: 99%

Ground- and excited-state properties of the polar and paramagnetic RbSr molecule: A comparative study

2014

View full text Add to dashboard Cite

This paper deals with the electronic structure of RbSr, a molecule possessing both a permanent magnetic and electric dipole moment in its own frame allowing its manipulation with external fields. Two complementary ab-initio approaches are used for the ground and lowest excited states: first, an approach relying on optimized effective core potentials with core polarization potentials based on a full configuration interaction involving three valence electrons, and second, an approach using a small-size effective core potential with 19 correlated electrons in the framework of coupled-cluster theory. We have found excellent agreement between these two approaches for the ground state properties including the permanent dipole moment. We have focused on studies of excited states correlated to the two lowest asymptotes Rb(5p 2 P )+Sr(5s 2 1 S) and Rb(5s 2 S)+Sr(5s5p 3 P ) relevant for ongoing experiments on quantum degenerate gases. We present also the Hund c) case potential curves obtained using atomic spin-orbit constants. These potential curves are an excellent starting point for experimental studies of molecular structure of RbSr using high-resolution spectroscopy.

show abstract

“…Note that in Table 2, the computed 0 + level energies have been corrected by 0.24cm −1 , as the extraction of potential curves from Ref. 32 relies on the latter value. Our measurement is entirely limited by the precision of our wavemeters and could be greatly improved by e.g.…”

Section: Two-photon Dark State Resonance Spectroscopymentioning

confidence: 99%

Molecular spectroscopy for ground-state transfer of ultracold RbCs molecules

Debatin

Takekoshi

Rameshan

et al. 2011

Phys. Chem. Chem. Phys.

116

View full text Add to dashboard Cite

We perform one-and two-photon high resolution spectroscopy on ultracold samples of RbCs Feshbach molecules with the aim to identify a suitable route for efficient ground-state transfer in the quantum-gas regime to produce quantum gases of dipolar RbCs ground-state molecules. One-photon loss spectroscopy allows us to probe deeply bound rovibrational levels of the mixed excited (A 1 Σ + − b 3 Π 0 ) 0 + molecular states. Two-photon dark state spectroscopy connects the initial Feshbach state to the rovibronic ground state. We determine the binding energy of the lowest rovibrational level |v ′′ = 0, J ′′ = 0 of the X 1 Σ + ground state to be D X 0 = 3811.5755(16) cm −1 , a 300-fold improvement in accuracy with respect to previous data. We are now in the position to perform stimulated two-photon Raman transfer to the rovibronic ground state.

show abstract

Spectroscopic data, spin-orbit functions, and revised analysis of strong perturbative interactions for theA 1Σ+andb <

Cited by 60 publications

References 61 publications

Theoretical study of spin–orbit and Coriolis coupling among the low-lying states of Rb2 and Cs2

Theoretical study of spin–orbit and Coriolis coupling among the low-lying states of Rb2 and Cs2

Ground- and excited-state properties of the polar and paramagnetic RbSr molecule: A comparative study

Molecular spectroscopy for ground-state transfer of ultracold RbCs molecules

Contact Info

Product

Resources

About