In this article, the AgIn(WO 4 ) 2 photocatalyst was prepared by coprecipitation using Na 2 WO 4 , AgNO 3 and In(NO 3 ) 3 as raw materials. The photocatalyst was characterised by transmission electron microscopy, X-ray powder diffraction and UV-vis diffuse reflectance spectroscopy. The photocatalytic activity of the AgIn(WO 4 ) 2 was evaluated by photocatalytic reduction of Cr 2 O 2À 7 and nitrobenzene. The results showed that, when the reaction solution was illuminated for 60 min and 10 h, respectively, the photoreduction efficiency of Cr 2 O 2À 7 and production efficiency of aniline were 88.6% and 48.7%, respectively. The effect of heat treatment conditions on the photocatalytic activity of the photocatalyst was also investigated. The best preparation condition is approximately 550 C for 5 h. The mechanisms of influence on the photocatalytic activity were also discussed.