Spectroscopic Properties of Erbium-Doped Oxyfluoride Phospho-Tellurite Glass and Transparent Glass-Ceramic Containing BaF2 Nanocrystals

Leśniak, Magdalena; Żmojda, Jacek; Kochanowicz, Marcin; Miluski, Piotr; Baranowska, Agata; Mach, Gabriela; Kuwik, Marta; Pisarska, Joanna; Pisarski, Wojciech A.; Dorosz, Dominik

doi:10.3390/ma12203429

Cited by 27 publications

(14 citation statements)

References 139 publications

(209 reference statements)

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“…A single report describes tellurite glasses with up to 50 mol% of PbF 2 , even if the glassy state of the resulting samples obtained by melt-quenching is not demonstrated [ 51 ]. Fluorotellurite glass-ceramics containing calcium and barium fluoride crystalline nanocrystals were also reported but with a final translucent aspect associated to crystallites scattering [ 52 , 53 , 54 , 55 ].…”

Section: Introductionmentioning

confidence: 99%

Transparent Glasses and Glass-Ceramics in the Ternary System TeO2-Nb2O5-PbF2

et al. 2021

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Transparent fluorotellurite glasses were prepared by melt-quenching in the ternary system TeO2-Nb2O5-PbF2. The synthesis conditions were adjusted to minimize fluorine loss monitored as HF release. It was found that 10 mol% of Nb2O5 is the optimum content for PbF2 incorporation up to 35 mol% in the tellurite matrix without loss of glass forming ability. Such glass compositions exhibit a wide optical window from 380 nm to about 6 μm. Crystallization properties were carefully investigated by thermal analysis and compositions with higher PbF2 contents exhibit preferential precipitation of lead oxyfluoride Pb2OF2 at lower temperatures. The lead oxyfluoride crystallization mechanism is also governed by a volume nucleation, barely reported in tellurite glasses. Eu3+ doping of these glass compositions also promotes a more efficient nucleation step under suitable heat-treatments, resulting in transparent Eu3+-doped glass-ceramics whereas undoped glass-ceramics are translucent. Finally, Eu3+ spectroscopy pointed out a progressive, more symmetric surrounding around the rare earth ions with increasing PbF2 contents as well as higher quantum efficiencies. These new fluorotellurite glass compositions are promising as luminescent hosts working in the middle infrared.

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Section: Introductionmentioning

confidence: 99%

Transparent Glasses and Glass-Ceramics in the Ternary System TeO2-Nb2O5-PbF2

et al. 2021

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“…The conventional melt-quenching method followed by controlled heat-treatment at specified time and temperature conditions is currently the most widely used technique for fabricating the class of oxyfluoride GCs [32][33][34][35][36]. On the other hand, the high melting temperatures of glass-forming components (e.g., 1450 • C, 1500 • C [37][38][39]) increase the risk of volatilization of the fluoride compounds, which may adversely affect the crystallization process of the fluoride fraction.…”

Section: Introductionmentioning

confidence: 99%

Energy Transfer Study on Tb3+/Eu3+ Co-Activated Sol-Gel Glass-Ceramic Materials Containing MF3 (M = Y, La) Nanocrystals for NUV Optoelectronic Devices

2020

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In the present work, the Tb3+/Eu3+ co-activated sol-gel glass-ceramic materials (GCs) containing MF3 (M = Y, La) nanocrystals were fabricated during controlled heat-treatment of silicate xerogels at 350 °C. The studies of Tb3+ → Eu3+ energy transfer process (ET) were performed by excitation and emission spectra along with luminescence decay analysis. The co-activated xerogels and GCs exhibit multicolor emission originated from 4fn–4fn optical transitions of Tb3+ (5D4 → 7FJ, J = 6–3) as well as Eu3+ ions (5D0 → 7FJ, J = 0–4). Based on recorded decay curves, it was found that there is a significant prolongation in luminescence lifetimes of the 5D4 (Tb3+) and the 5D0 (Eu3+) levels after the controlled heat-treatment of xerogels. Moreover, for both types of prepared GCs, an increase in ET efficiency was also observed (from ηET ≈ 16% for xerogels up to ηET = 37.3% for SiO2-YF3 GCs and ηET = 60.8% for SiO2-LaF3 GCs). The changes in photoluminescence behavior of rare-earth (RE3+) dopants clearly evidenced their partial segregation inside low-phonon energy fluoride environment. The obtained results suggest that prepared SiO2-MF3:Tb3+, Eu3+ GC materials could be considered for use as optical elements in RGB-lighting optoelectronic devices operating under near-ultraviolet (NUV) excitation.

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“…In the diffraction patterns of the glass heated at 650 °C in three (15ZnO_6500C_3h) and five (15ZnO_6500C_5 h) hours, the peaks were observed. They were assigned to the zinc gallium oxide (ZnGa 2 O 4 ) cubic phase (JCPDF: 01-086-0413) [ 35 ]. The average size of the nanocrystals was ca.…”

Section: Resultsmentioning

confidence: 99%

Structure and Luminescence Properties of Transparent Germanate Glass-Ceramics Co-Doped with Ni2+/Er3+ for Near-Infrared Optical Fiber Application

et al. 2021

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An investigation of the structural and luminescent properties of the transparent germanate glass-ceramics co-doped with Ni2+/Er3+ for near-infrared optical fiber applications was presented. Modification of germanate glasses with 10–20 ZnO (mol.%) was focused to propose the additional heat treatment process controlled at 650 °C to obtain transparent glass-ceramics. The formation of 11 nm ZnGa2O4 nanocrystals was confirmed by the X-ray diffraction (XRD) method. It followed the glass network changes analyzed in detail (MIR—Mid Infrared spectroscopy) with an increasing heating time of precursor glass. The broadband 1000–1650 nm luminescence (λexc = 808 nm) was obtained as a result of Ni2+: 3T2(3F) → 3A2(3F) octahedral Ni2+ ions and Er3+: 4I13/2 → 4I15/2 radiative transitions and energy transfer from Ni2+ to Er3+ with the efficiency of 19%. Elaborated glass–nanocrystalline material is a very promising candidate for use as a core of broadband luminescence optical fibers.

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Spectroscopic Properties of Erbium-Doped Oxyfluoride Phospho-Tellurite Glass and Transparent Glass-Ceramic Containing BaF2 Nanocrystals

Cited by 27 publications

References 139 publications

Transparent Glasses and Glass-Ceramics in the Ternary System TeO2-Nb2O5-PbF2

Transparent Glasses and Glass-Ceramics in the Ternary System TeO2-Nb2O5-PbF2

Energy Transfer Study on Tb3+/Eu3+ Co-Activated Sol-Gel Glass-Ceramic Materials Containing MF3 (M = Y, La) Nanocrystals for NUV Optoelectronic Devices

Structure and Luminescence Properties of Transparent Germanate Glass-Ceramics Co-Doped with Ni2+/Er3+ for Near-Infrared Optical Fiber Application

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