1973
DOI: 10.1021/j100630a012
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Spectroscopy and chemistry of aprotic neodymium(3+) ion laser liquids

Abstract: Publication costs assisted by GTE LaboratoriesMeasurements have been made on various aspects of the spectroscopy of the SeOClz and aprotic Nd3+ laser liquids, with emphasis on the latter. Unusual features in the chemical behavior are described and some apparent inconsistencies resolved. The formation of complex POzCl2-Lewis acid groups is deemed to be a major factor in the solubilizing of the Nd3+ ion in Poc13 solution. A consistent and COherent model is proposed to explain the observations.(1)

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Cited by 23 publications
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“…To enhance the emission efficiency of an Nd 3+ ion in solution, Heller et al proposed that Nd 3+ ions should be surrounded by ligands or solvent molecules with low-energy vibrations. , Their work led to the first successful use of SeOCl 2 and POCl 3 as a solvent of Nd 3+ for laser emission in liquid system. Although the emission efficiency was improved significantly by using such inorganic aprotic media, they were not appropriate for practical use because of their unstability and high toxicity.…”
Section: Introductionmentioning
confidence: 99%
“…To enhance the emission efficiency of an Nd 3+ ion in solution, Heller et al proposed that Nd 3+ ions should be surrounded by ligands or solvent molecules with low-energy vibrations. , Their work led to the first successful use of SeOCl 2 and POCl 3 as a solvent of Nd 3+ for laser emission in liquid system. Although the emission efficiency was improved significantly by using such inorganic aprotic media, they were not appropriate for practical use because of their unstability and high toxicity.…”
Section: Introductionmentioning
confidence: 99%