The anisotropy of optical absorption saturation by intense linearly polarized light pulses is measured with subpicosecond resolution in GaAs at 77 K, at a photon energy slightly above the band gap. For an electron-hole pair density of about 6xl0 17 cm -3 , the momentum orientational relaxation time is determined to be 190 fs, most likely due to carrier-carrier scattering.PACS numbers: 72.20.JvThe development of picosecond, and now femtosecond lasers, has allowed direct studies of the dynamics of hot photoexcited carriers in semiconductors. 1 "" 6 These works have shown that, on a very short time scale (usually less than 1 ps), a quasiequilibrium electron-hole (e-h) plasma is established through the combined action of carriercarrier and carrier-phonon interactions. While the subsequent cooling of this e-h plasma towards the lattice temperature is well documented, 6 little is known about the primary stage of the carrier relaxation. Recently Tang and Erskine 5 have observed in Al x Gai_ x As femtosecond transients due to the energy relaxation of individual Bloch states. On the other hand, linearly polarized light generates carriers with an anisotropic momentum distribution; the observation on a steady-state basis of a polarized photoluminescence 7 is a clear manifestation of the primary stage of carrier relaxation, since the anisotropy of their momentum distribution disappears within a few electronic collisions. Related to this, Smirl et al. observed picosecond transient orientational gratings 3 due to anisotropic state filling in germanium, but could only deduce an upper limit of the relaxation time.We report a direct determination of the orientational relaxation time (in k space) of e-h pairs created by linearly polarized subpicosecond pulses in GaAs at 77 K. The polarized pump pulse increases the sample transmission by filling states near the band edge, with an anisotropic momentum distribution. This anisotropy is measured through probing, by a weaker test pulse, the corresponding anisotropy of optical absorption saturation. Polarization variations are recorded as a function of the relative delay between pump and test pulses; hence this technique is the time-domain counterpart of polarization spectroscopy, 8 well known for its high sensitivity. In the present case, it provides direct information about the randomization of the initially anisotropic distribution of carriers. In order to have the carrier-carrier interactions as the dominant scattering mechanism, we tuned the excitation wavelength at 806 nm, creating e-h pairs with excess energy less than the threshold for optical phonon emission.The connection between our optical measurement and the e -h momentum distributions is as follows. The transition rate between valence and conduction states of wave vector k is proportional to the square of the matrix element P cv (k), projected on to the optical wave polarization e f (/=p or t for pump or test). In the present case of small carrier kinetic energy, isotropic parabolic bands can be assumed. For linear polariza...