“…27,33,41,42,44,[46][47][48][49][50][51][52][53][54] Based on that, molecular electronic devices such as rectifiers, switches or pumps were proposed that operate by an external field driving the junction. 27,[55][56][57][58][59][60][61][62][63] A variety of theoretical approaches are available to describe electron transport across a molecular junction in the presence of external driving. 31,32,39,[64][65][66] Thereby, the effect of a time-dependent field is described by time-dependent parameters of the Hamiltonian.…”