The degenerate three-photon absorption coefficient and cross section associated with the interband
transition 1S3/2(h)–1S(e)
for CdTe spherical quantum dots have been calculated within the two-level
model. The band structure and wavefunctions are derived from the
8 × 8 k·p
Hamiltonian which takes into account the conduction–valence band coupling and the
mixing of the valence states. The transition selection rules for three-photon absorption in
the case of linearly polarized incident light are discussed in detail. The size-dependent
three-photon absorption spectra versus incident photon energy have been obtained and
analyzed.