In a number of recent experiments, holmium has been shown to promote spin triplet pairing when in proximity to a spin singlet superconductor. The condition for the support of spin triplet pairing is that the ferromagnet should have an inhomogeneous magnetic state at the interface with the superconductor. Here we use Andreev reflection spectroscopy to study the properties of single ferromagnet/superconductor interfaces formed of holmium and niobium, as a function of the contact resistance of the junction between them. We find that both single crystal and c-axis oriented thin film holmium show unusual behavior for low junction contact resistance, characteristic of spin mixing type properties, which are thought necessary to underpin spin triplet formation. We also explore whether this signature is observed when the junction is formed of Ni 19 Pd 81 and niobium.