White cement (WC)
represents a low-cost, sustainable, and nontoxic
alternative adsorbent for phosphate (PO4
3–) adsorption from aqueous solutions. The composite central rotational
design (CCRD) method was applied to optimize adsorption through kinetic,
equilibrium, and thermodynamic batch studies. For fixed-bed column
studies, the CCRD method evaluated the influent flow rate and adsorbent
mass. The high levels of calcium oxide (CaO, 65%) observed in WC influenced
the adsorption that achieved an efficiency of 97% under the optimal
condition. Pseudo-first and pseudo-second order models better represented
adsorption (54.68 mg g–1; pH 7.5). Redlich–Peterson,
Freundlich, and Langmuir models better represented adsorption (59.53
mg g–1) at the equilibrium time (60 min). Adsorption
showed spontaneous reactions of an exothermic nature. The proposed
mechanisms are related to adsorption onto iron and aluminum hydroxides
and oxides, precipitation of calcium phosphates, and electrostatic
attraction. Non-PO4
3– desorption was
observed under the evaluated conditions. In the fixed-bed column assays,
an influent flow rate of 3.50 mL min–1 and an adsorbent
mass of 0.27 g were verified as optimal conditions. WC exhibited phosphate
removal efficiencies of 90% for raw effluent and 98% for primary-treated
effluent from a corn flour processing industry with initial PO4
3– concentrations of 1.35 and 0.19 mg L–1, respectively. Finally, WC demonstrated a promising
capacity as an adsorbent for phosphate removal.