Spray‐Dried Mesoporous Mixed Cu‐Ni Oxide@Graphene Nanocomposite Microspheres for High Power and Durable Li‐Ion Battery Anodes

Abstract

Exfoliated graphene‐wrapped mesoporous Cu‐Ni oxide (CNO) nanocast composites are developed using a straightforward nanostructure engineering strategy. The synergistic effect of hierarchical mesoporous CNO nanobuilding blocks that are homogeneously wrapped by graphene nanosheets (GNSs) using a rapid spray drying technique effectively preserves the electroactive species against the volume changes resulting from the charge/discharge process. Owing to the intriguing structural/morphological features arising from the caging effect of exfoliated graphene sheets, these 3D/2D CNO@GNS nanocomposite microspheres are promising as high‐performance Li‐ion battery anode materials. They exhibit unprecedented electrochemical behavior, such as high reversible specific capacity (initial discharge capacities exceeding 1700 mAh g−1 at low 0.1 mA g−1, stable 850 and 730 mAh g−1 at 1 and 5 mA g−1 after 800 and 1300 cycles, respectively, and higher than 400 mAh g−1 at very high current density of 10 mA g−1 after more than 2000 cycles), excellent coulombic efficiency and long‐term stability (more than 3000 cycles with >55% capacity retention) at high current density that are remarkable compared to most transition metal oxides and nanocomposites prepared by conventional techniques. This simple, yet innovative, material design is inspiring to develop advanced conversion materials for Li‐ion batteries or other energy storage devices.

Supraparticles for Sustainability

“…SPs have also been reported for more exotic anode active materials like micrometer‐sized assemblies of ZnS/CoS/CoS 2 @N‐doped NPs, [ 129 ] spray‐dried mesoporous mixed Cu–Ni‐oxide@graphene nanocomposites, [ 130 ] and nanoporous TiNb 2 O 7 /C composite microspheres. [ 131 ] Closely related to the lithium‐ion technology are sodium‐ion batteries that generally possess lower energy densities.…”

Mesoporous Nanocast Electrocatalysts for Oxygen Reduction and Oxygen Evolution Reactions

“…To do this, there are various techniques depending on the templates and precursors. Wet impregnation [26,28], incipient wetness [26,27], two-solvent method [26], melt infiltration [30,31] and one-step (molten salts) impregnation [32,33] are the most common. In the wet impregnation pathway (or wetness impregnation-calcination method), an excess amount of solvent as compared to the total pore volume of the porous mold is used.…”

A Pair of NiCo2O4 and V2O5 Nanowires Directly Grown on Carbon Fabric for Highly Bendable Lithium‐Ion Batteries

“…It is well known that transition metal oxide (TMO) based electrodes have high specific capacity. Moreover, mixed‐valence TMO with two or more cations is commonly reported for enhanced capacity and stability . However, since nickel cobalt oxide has no lithium ions in initial states, the anode was pre‐lithiated before the cell‐fabrication and paired with the vanadium oxide nanowires to form a full cell, instead of using lithium metal as the anode.…”