While solid substrates are often idealized as being perfectly
smooth,
all real surfaces possess some level of topographical and chemical
heterogeneity. This heterogeneity can greatly influence droplet dynamics.
Mathematical models based on lubrication theory that account for surface
roughness reveal how topographical defects induce contact-line pinning
and affect the deposition patterns of colloidal particles suspended
in the droplet. Contact-line pinning profoundly changes the behavior
of droplet evaporation on horizontal and inclined impermeable substrates
and droplet absorption on horizontal permeable substrates. Models
accounting for surface roughness yield predictions that are qualitatively
consistent with experimental observations and also provide insight
into the underlying physical mechanisms. These models are a foundation
for the exploration of a rich array of problems concerning droplet
dynamics which are of both fundamental and practical interest.