Abstract. Surface-bounded exospheres have been detected at the Moon, Mercury, and Europa and almost certainly exist about other objects. Historically, the first of these systems to be observed was the lunar exosphere, where He and Ar were detected by the Apollo spacecraft. The Hermean exosphere is archetypical of these systems in that it is part of a coupled system including the surface and magnetosphere interacting dynamically with the solar wind and fields. Studies of the Hermean exosphere heretofore have neglected or only superficially considered these interactions. We will review the current state of knowledge of the exospheres of Mercury and the Moon and discuss areas in which our knowledge is most incomplete. We will focus on the exosphere as part of a coupled system including the surface at its base and the particle, field, and interplanetary environment as both a source and sink for neutrals. Apollo era instruments made unambiguous detections of 36mr, 4ømr,
Early Work and OverviewIn a review prior to the Mariner 10 encounter, Banks et al. [1970] reported no observational evidence for the presence of an atmosphere about Mercury. They predicted an exosphere (N < 2 x 10 TM cm -2) or thin atmosphere resulting from diffusion or effusion from the interior, solar wind implantation with subsequent thermal evaporation, or sputtering. By scaling terrestrial noble gas production and diffusion rates and assuming a lunar-like solar wind interaction, they suggested that the most abundant constituents should be the noble gases derived from the solar wind and radiogenic sources, the most abundant being 4He, followed by 4øAr and 2øNe.