Stability Trends of the Rare Earth Complexes

A series of rare earth element (REE) mixed-anion 5,5′azobis(1H-tetrazol-1-ide)-carbonate ([REE 2 (ZT) 2 CO 3 (H 2 O) 10 ]· 2H 2 O; REE = lanthanides plus yttrium) coordination compounds were synthesized, characterized, and analyzed. Syntheses by simple metathesis reactions under a CO 2 atmosphere were carried out at ambient (La-Gd and Ho) and elevated pressures (55 bar; Tb, Dy, Er, Tm, Yb, and Y). The resulting crystalline materials were characterized principally by single-crystal X-ray diffraction and vibrational spectroscopy (infrared and Raman). All materials are structurally isotypic, crystallizing in the space [a]

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Azobis[tetrazolide]‐Carbonates of the Lanthanides – Breaking the Gadolinium Break

Müller

Knöll

Herrmann

et al. 2018

Eur J Inorg Chem

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Metal-organic complexes in geochemical processes: temperature dependence of the standard thermodynamic properties of aqueous complexes between metal cations and dicarboxylate ligands

Prapaipong

Shock

Koretsky

1999

Geochimica et Cosmochimica Acta

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Stability Trends of the Rare Earth Complexes

Cited by 2 publications

References 18 publications

Azobis[tetrazolide]‐Carbonates of the Lanthanides – Breaking the Gadolinium Break

Azobis[tetrazolide]‐Carbonates of the Lanthanides – Breaking the Gadolinium Break

Metal-organic complexes in geochemical processes: temperature dependence of the standard thermodynamic properties of aqueous complexes between metal cations and dicarboxylate ligands

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