Stabilization of propene molybdenum and tungsten half–sandwich complexes by intramolecular coordination of a thioether function

Hanzl, Lukáš; Vinklárek, Jaromír; Dostál, Libor; Císařová, Ivana; Litecká, Miroslava; Honzíček, Jan

doi:10.1039/d3ra03383j

RSC Adv.

2023

DOI: 10.1039/d3ra03383j

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Stabilization of propene molybdenum and tungsten half–sandwich complexes by intramolecular coordination of a thioether function

Lukáš Hanzl,

Jaromír Vinklárek,

Libor Dostál

et al.

Abstract: The stabilizing effect of an intramolecularly coordinated thioether function in propene complexes of molybdenum and tungsten is reported.

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Cyclopentadienyl Molybdenum(II) Compounds Bearing Ether and Thioether Functions in the Side Chain: Synthesis, Characterization, and Cytotoxic/Cytostatic Studies

Hanzl,

Vinklárek,

Honzíček

et al. 2023

ChemPlusChem

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A series of molybdenum(II) compounds [(η5‐Cp’)Mo(CO)2(L2)][BF4] (Cp’ = C5H4(CH2)2SPh, C9H6(CH2)2OMe, L2 = N,N‐chelating ligand) have been synthesized and characterized by spectroscopic and analytical methods including X‐ray crystallography. The in vitro assay on human leukemia cells MOLT‐4 has shown that the substitution in the π‐ligand in combination with suitable N,N‐chelating ligand can lead to species with cytotoxicity considerably higher than reported to cisplatin. Unusually high activity was observed for compounds bearing phenanthroline ligands [{η5‐C9H6(CH2)2OMe}Mo(CO)2(3,4,7,8‐Me4phen)][BF4] (IC50 = 0.7 ± 0.3 μM) and [{η5‐C9H6(CH2)2OMe}Mo(CO)2(4,7‐Ph2phen)][BF4] (IC50 values 0.8 ± 0.4 μM).

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Cyclopentadienyl Molybdenum(II) Compounds Bearing Ether and Thioether Functions in the Side Chain: Synthesis, Characterization, and Cytotoxic/Cytostatic Studies

Hanzl,

Vinklárek,

Honzíček

et al. 2023

ChemPlusChem

View full text Add to dashboard Cite

show abstract

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Stabilization of propene molybdenum and tungsten half–sandwich complexes by intramolecular coordination of a thioether function

Abstract: The stabilizing effect of an intramolecularly coordinated thioether function in propene complexes of molybdenum and tungsten is reported.

Cited by 1 publication

References 48 publications

Cyclopentadienyl Molybdenum(II) Compounds Bearing Ether and Thioether Functions in the Side Chain: Synthesis, Characterization, and Cytotoxic/Cytostatic Studies

Cyclopentadienyl Molybdenum(II) Compounds Bearing Ether and Thioether Functions in the Side Chain: Synthesis, Characterization, and Cytotoxic/Cytostatic Studies

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