Stabilized Substituted Ions and Radicals Bearing One Heteroatom (R1R2C−X, R1R2C+X, R1R2C·X)

Schmidt, Andreas

doi:10.1016/b0-08-044655-8/00042-8

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“…The key step in this transformation is α-deprotonation of a doubly activated methylene group to give a nitrile-stabilized carbanion. Species of this type are useful intermediates in organic synthesis . α-Phosphanyl anions are less abundant but have also been prepared …”

Section: Resultsmentioning

confidence: 99%

Synthesis and Characterization of an Unsymmetrical 1,2-Diphosphinoethanide Complex

2011

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A palladium 1,2-ethylene-bisphosphine complex prepared by diphosphination of acrylonitrile and subsequent complexation undergoes facile and reversible C deprotonation at a backbone carbon atom. The 1,2-diphosphinoethanide complex that formed was characterized by spectroscopic data and a single-crystal X-ray diffraction study. The reaction may explain the previously observed configurational lability of coordinated 1,2-bisphosphine ligands with electron-withdrawing substituents.

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Section: Resultsmentioning

confidence: 99%

Synthesis and Characterization of an Unsymmetrical 1,2-Diphosphinoethanide Complex

2011

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Stabilized Substituted Ions and Radicals Bearing One Heteroatom (R¹R²C^‐X, R¹R²C⁺X, R¹R²CX)

Schmidt¹

2005

ChemInform

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Stabilized Substituted Ions and Radicals Bearing One Heteroatom (R1R2C−X, R1R2C+X, R1R2C·X)

Cited by 2 publications

References 97 publications

Synthesis and Characterization of an Unsymmetrical 1,2-Diphosphinoethanide Complex

Synthesis and Characterization of an Unsymmetrical 1,2-Diphosphinoethanide Complex

Stabilized Substituted Ions and Radicals Bearing One Heteroatom (R¹R²C^‐X, R¹R²C⁺X, R¹R²CX)

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Stabilized Substituted Ions and Radicals Bearing One Heteroatom (R1R2C−X, R1R2C+X, R1R2C·X)

Cited by 2 publications

References 97 publications

Synthesis and Characterization of an Unsymmetrical 1,2-Diphosphinoethanide Complex

Synthesis and Characterization of an Unsymmetrical 1,2-Diphosphinoethanide Complex