Sb-based materials are widely used in alkali metalion batteries due to large specific capacity, low cost, and a suitable operating voltage platform. However, they suffer from tardy dynamic performance and structural instability, along with a vague storage mechanism for alkali metal ion (Li + /K + ) confining their further popularization. Herein, a scalable strategy is proposed to make Sb nanoparticles encapsulated in the N, S, and F co-doping