2020
DOI: 10.1002/jms.4595
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Stable isotope ratio analysis combined with inductively coupled plasma‐mass spectrometry for geographical discrimination between Italian and foreign saffron

Abstract: Seventy-six samples of saffron were analysed through inductively coupled plasmamass spectrometry (ICP-MS) and stable isotope ratio analysis. The dataset was formed by 67 samples harvested in different areas of Italy, Morocco and Iran, and nine samples purchased in the Italian market. For the first time, 42 elements and five stable isotopes (δ 13 C, δ 15 N, δ 34 S, δ 2 H and δ 18 O) were considered to carry out the discrimination of the samples on the basis of their geographical origin. Combined ICP-MS and isot… Show more

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Cited by 21 publications
(10 citation statements)
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“…More recent attention has focused on the development of novel methodologies for tracking the spices/herbs supply chain. In particular, the last five years, ICP-MS has a dynamic appearance in the field of geographical origin authentication of spices and herbs [ 200 , 201 , 202 , 203 , 204 , 205 , 206 , 207 , 208 , 209 , 210 , 211 ]. Special attention has been paid to saffron due to its relatively high value.…”
Section: Discussionmentioning
confidence: 99%
See 1 more Smart Citation
“…More recent attention has focused on the development of novel methodologies for tracking the spices/herbs supply chain. In particular, the last five years, ICP-MS has a dynamic appearance in the field of geographical origin authentication of spices and herbs [ 200 , 201 , 202 , 203 , 204 , 205 , 206 , 207 , 208 , 209 , 210 , 211 ]. Special attention has been paid to saffron due to its relatively high value.…”
Section: Discussionmentioning
confidence: 99%
“…Geographical discrimination was achieved based on the analysis of the most efficient variables which were: Li, B, Na, Ga, Rb, Sr, Zr, Nb, Cs, Ba, Sm, and Hf. Perini and co-workers [ 206 ] worked on similar project by combining stable isotope ratio and multi-elemental analysis. The authors analyzed 67 saffron samples from Italy, Iran and Morocco succeeded the geographical discrimination based on the elements δ 13 C, δ 34 S, δ 15 N, δ 18 O, δ 2 H, K, Cr, Mn, Ni, Zn, Rb, Sr, Mo, Cs, Nd, Eu, Pb, and Ni.…”
Section: Discussionmentioning
confidence: 99%
“…For a sample type not previously covered by these ASUs, Perini et al 185 measured 42 elements by ICP-MS and stable isotope analysis (δ 13 C, δ 15 N, δ 34 S, δ 2 H and δ 18 O) in 76 saffron samples from Morocco, Iran and Italy , produced between 2016 and 2019. Saffron has historically been a highly prized spice and, as such, production has expanded to many countries across the planet, away from the traditional growing areas of Turkey, Greece, Iran and Italy.…”
Section: Applications: Food and Beveragesmentioning
confidence: 99%
“…Stable isotope ratio analysis of light elements (C, N, S, O and H) has been widely used to investigate food authenticity. Examples are reported for wine (Dordevic et al, 2013), vinegar (Camin et al, 2013;Perini et al, 2014), orange juice (Simpkins et al, 1999), coffee (Santato et al, 2012), olive oil (Camin et al, 2010), cheese (Camin et al, 2012;Pianezze et al, 2020), saffron (Perini et al, 2020), tomatoes (Bontempo et al, 2020;Bontempo et al, 2011), honey (Bontempo et al, 2017), cereals (Asfaha et al, 2011) and also food supplements (Perini et al, 2017). It has also been recognised, since the 90s by several standardisation organizations (CEN, AOAC, OIV, EU Reg.)…”
Section: Introductionmentioning
confidence: 99%