Stable isotopes of hydrogen and oxygen in surface water and ground water at selected sites on or near the Idaho National Engineering Laboratory, Idaho

Stable isotope data (2H and 18O) were used in conjunction with chlorofluorocarbon (CFC) and tritium/helium‐3 (3H/3He) data to determine the fraction and age of irrigation water in ground water mixtures from farmed parts of the Eastern Snake River Plain (ESRP) Aquifer in south‐central Idaho. Two groups of waters were recognized: (1) regional background water, unaffected by irrigation and fertilizer application, and (2) mixtures of irrigation water from the Snake River with regional background water. New data are presented comparing CFC and 3H/3He dating of water recharged through deep fractured basalt, and dating of young fractions in ground water mixtures. The 3H/3He ages of irrigation water in most mixtures ranged from about zero to eight years. The CFC ages of irrigation water in mixtures ranged from values near those based on 3H/3He dating to values biased older than the 3H/3He ages by as much as eight to 10 years. Unsaturated zone air had CFC‐12 and CFC‐113 concentrations that were 60% to 95%, and 50% to 90%, respectively, of modern air concentrations and were consistently contaminated with CFC‐11. Irrigation water diverted from the Snake River was contaminated with CFC‐11 but near solubility equilibrium with CFC‐12 and CFC‐113. The dating indicates ground water velocities of 5 to 8 m/d for water along the top of the ESRP Aquifer near the southwestern boundary of the Idaho National Engineering and Environmental Laboratory (INEEL). Many of the regional background waters contain excess terrigenic helium with a 3He/4He isotope ratio of 7 × 10−6 to 11 × 10−6 (R/Ra= 5 to 8) and could not be dated. Ratios of CFC data indicate that some rangeland water may contain as much as 5% to 30% young water (ages of less than or equal to two to 11.5 years) mixed with old regional background water. The relatively low residence times of ground water in irrigated parts of the ESRP Aquifer and the dilution with low‐NO3 irrigation water from the Snake River lower the potential for NO3 contamination in agricultural areas.

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Completion summary for Borehole TAN-2336 at Test Area North, Idaho National Laboratory, Idaho

Twining¹,

Treinen²,

Trcka³

2023

Scientific Investigations Report

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Stable isotopes of hydrogen and oxygen in surface water and ground water at selected sites on or near the Idaho National Engineering Laboratory, Idaho

Abstract: The relative isotopic ratios of hydrogen and oxygen are reported as delta 2H (2j2H) and as delta le0 (6l80), respectively. The values of

Cited by 3 publications

References 12 publications

The use of geochemical mass-balance and mixing models to determine groundwater sources

The use of geochemical mass-balance and mixing models to determine groundwater sources

Age of Irrigation Water in Ground Water from the Eastern Snake River Plain Aquifer, South‐Central Idaho

Completion summary for Borehole TAN-2336 at Test Area North, Idaho National Laboratory, Idaho

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