2023
DOI: 10.2174/1570193x19666220331155015
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State of the Art in Industrial Application of Amino-1,2,4-Triazoles

Abstract: The review summarizes information on the industrial use of 3- and 4-amino-1,2,4-triazoles, the basic raw material for the industry of fine organic synthesis. A description of the existing production methods for the synthesis of 3- and 4-amino-1,2,4-triazoles and some methods of obtaining in laboratory conditions is given. Three main areas of use of these amines and their derivatives have been identified: agriculture, medicine, high-energy substances and gas-generating compositions. It has been shown that one o… Show more

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Cited by 3 publications
(3 citation statements)
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“…In this context, the 1,2,4-triazole ring caught our attention due to its known effectiveness as part of corrosion inhibitors for lowcarbon steel, [20][21][22][23][24][25][26] and to its use as a building block of lightemitting devices in organic electronic applications due to the luminescent properties and ready thin-lm formation of several of its derivatives. [27][28][29][30][31] Moreover, it has recently become an important synthon for Metal-Organic Frameworks (MOFs) and coordination polymers. Since the molecular packing of 1,2,4-triazole derivatives tends to be directed by H-bonding interactions, it allows the controlled bottom-up construction of MOFs and it has been applied to Fe(II) coordination polymers that present spin-crossover behavior.…”
Section: Introductionmentioning
confidence: 99%
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“…In this context, the 1,2,4-triazole ring caught our attention due to its known effectiveness as part of corrosion inhibitors for lowcarbon steel, [20][21][22][23][24][25][26] and to its use as a building block of lightemitting devices in organic electronic applications due to the luminescent properties and ready thin-lm formation of several of its derivatives. [27][28][29][30][31] Moreover, it has recently become an important synthon for Metal-Organic Frameworks (MOFs) and coordination polymers. Since the molecular packing of 1,2,4-triazole derivatives tends to be directed by H-bonding interactions, it allows the controlled bottom-up construction of MOFs and it has been applied to Fe(II) coordination polymers that present spin-crossover behavior.…”
Section: Introductionmentioning
confidence: 99%
“…[32][33][34][35][36][37] In light of the aforementioned considerations, the impact of incorporating a 4-amino-1,2,4-triazole (51) moiety into the 7-DAC nucleus was investigated to assess its inuence on the solid-state organization. 27,31,38 The amino group (-NH 2 ) is a plausible precursor to an imine or Schiff base p-bridge for the targeted derivative (Scheme 1). The imine linkage, R-C]N-R 0 , lacks the ability to be a classical hydrogen bond donor group.…”
Section: Introductionmentioning
confidence: 99%
“…Інша робота описує синтез нового ряду заміщених 1,2,4-триазолу, а саме 3,5-діарилпохідних-1,2,4-триазолу через бензоксинони [8] [3',2':4,5] тієно[2,3е] [1,2,4]триазолопіримідини та досліджено антимікробні властивості. З високими показниками активності авторами зазначеної роботи рекомендовано відповідні 10алкіл(арил)-8,9-дигідро-7Нциклопента [4',5']піридо [3',2':4,5]тієно[2 ,3е] [1,2,4]триазоло [4,3-с]піримідини та 10ізобутил-3-(метилтіо)-8,9-дигідро-7Нциклопента [4',5' ]піридо [3',2':4,5]тієно[2,3е] [1,2,4]триазоло [4,3-с] В оглядовій статті узагальнено відомості щодо промислового використання 3-та 4аміно-1,2,4-триазолів -основної сировини для промисловості тонкого органічного синтезу [22]. В ній наведено опис існуючих методів синтезу 3-та 4-аміно-1,2,4-…”
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