Transition probabilities of H 2 , HD, and D 2 Pc u 3 − S + a g 3 electric dipole, Pc u 3 − S + b u 3 discretecontinuum magnetic dipole, and electric quadrupole transitions have been calculated using accurate energies and ro-vibrational wave functions obtained from precise ab initio potential energy curves. The predissociation rates of the Pc u 3 (v N , ) levels by direct and indirect spinspin and spin-orbit coupling between Pc u 3 − S + b u 3 fine structure levels, have been also determined. The present investigation achieved good agreement with measured lifetimes of the Pc u 3 fine structure levels without adjustment. A comparison of the calculated and observed lifetimes of metastable H 2 , HD, and D 2 suggests that the Pc u 3 − S + b u 3 magnetic dipole and electric quadrupole transition moments underestimate the spontaneous emission rate of the metastable levels by ∼370 s −1 . The measured and calculated lifetimes of H 2 , HD, and D 2 fine structure levels are in very good agreement after the adjustment of 370 s −1 to the spontaneous decay rate of the Pc u 3 − S + b u 3 transition. The calculated energies, transition probabilities, and predissociation rates obtained in the present work, along with the P c u 3 state excitation function, are sufficient to determine the P c u 3 state emission cross section, the kinetic energy distribution of H(1s) atoms, and the energy deposition rate of the S + X g 1 − P c u 3 excitation. In a previous investigation by Berg and Ottinger (1994 J. Chem. Phys. 100 8746), the authors were forced to insert a large scale factor into the predissociation rate in order to reconcile with measured lifetimes. Errors introduced in the approximations made in the previous investigations are discussed in the text. The H 2 P c u 3 state has the second largest triplet state excitation cross section. Predissociation and spontaneous emission of the P c u 3 state plays an important role in the energy deposition of H 2 -dominated atmospheres.